（毕业设计论文）《不同的氧化液配方和氧化工艺对黑色微弧氧化膜的影响》.doc

摘要 普通微弧氧化处理为了提高其耐蚀、耐磨性能，所得陶瓷膜多为色调单一的银灰色或灰白色,对于装饰性却少有考虑。但在铝合金的工业应用中，对其表面色泽往往有特殊的要求。以黑色为例，由于其不仅庄重大方、 耐脏耐看 ,而且能消除或减少反光并提高供热性，因此在建筑、装饰、家电等领域有着广泛应用。 本文研究了不同的氧化液配方和氧化工艺对黑色微弧氧化膜的影响。通过调整氧化液中化学成分的比例以及氧化工艺参数，在ZL108基体上制备深色微弧氧化膜（主要为黑色）。运用多种材料现代分析手段，对微弧氧化陶瓷膜性能进行测试。这些性能包括陶瓷膜层的表面形貌观察；测量出膜层的厚度和硬度，通过数据的对比，可以得到不同氧化液配方和氧化工艺对微弧氧化膜层性能的影响，从中可得到最优化的氧化液配方和氧化工艺。 实验表明，通过调整配方中的成分比例，在Na2SiO3-NaOH- NaAlO2- NH4VO3体系中，调整NH4VO3浓度为1.5g/L时，可在ZL108基体表面上制备出较为黑色的陶瓷膜层。且陶瓷膜色泽比较稳定，膜层表面较光滑，厚度较为均匀，且具有较高的显微硬度。 硬度和厚度检测结果表明，随着电流密度和时间增大，陶瓷膜显微硬度和厚度逐渐增大，当电流密度为10A/dm2，氧化时间为30min，且电解液温度控制在25～50℃时，膜层的综合性能最好，且膜层颜色为深黑色。当电流过大或或温度过高时，均会会导致膜层质量下降。 关键词：ZL108；黑色微弧氧化；电流密度；硬度；厚度 Abstract Ordinary micro-arc oxidation process in order to improve the corrosion resistance and wear resistance, income is tonal ceramic membranes with single or grey, but seldom consider for decoration. But in aluminum industrial application, the surface color often have special requirements. With black, for example, not only because of its solemn generous, be able to bear or endure dirty, and can be able to bear or endure look to eliminate or reduce reflective and improve heating, therefore in construction, decoration, household appliances, etc is widely used. In this paper, performance testing is used to study the influence of different oxidation liquid formulation and oxidation process on the properties of black micro-arc oxidation ceramic coating. By adjusting the oxidation of the chemical composition and oxidation process parameters, the proportion of preparation ZL108 matrix in dark micro-arc oxidation film (mainly for the black). Using a variety of materials of modern analytical methods, micro-arc oxided ceramic membrane performance testing. These properties including ceramic membrane layer of surface morphology observation, Measuring the thickness of the coating hardness, through comparing the data of, can get different oxidation liquid formulation and oxidation process of micro-arc oxidation film, the influence of performance can be obtain