综合利用钛铁矿制备二氧化钛、钛酸锂和磷酸铁锂（可编辑）.doc

综合利用钛铁矿制备二氧化钛、钛酸锂和磷酸铁锂 第?21?卷第 10?期 中国有色金属学报? 2011?年?10?月? Vol.21?No.10? The?Chinese?Journal?of?Nonferrous?Metals? Oct.?2011? 文章编号:1004?0609201110?2697?12? 综合利用钛铁矿制备二氧化钛、钛酸锂和磷酸铁锂 李新海,伍 凌,王志兴,郭华军,彭文杰,吴飞翔? 中南大学 冶金科学与工程学院,长沙? 410083? 摘 要:以钛铁矿为原料,经机械活化?盐酸浸出得到水解钛渣和富铁浸出液;用?H O 将水解钛渣中的?Ti?配位 2 2? 溶出,得到配位浸出液,并以其为反应物制备纳米级片状的过氧钛化合物;该过氧钛化合物经洗涤、煅烧制备得 到纳米级片状的?TiO ,其纯度高达?99.31%质量分数。将过氧钛化合物与?Li CO 混合,球磨后煅烧合成性能优 2 2 3? 良的锂离子电池负极材料 Li Ti O 。以富铁浸出液为原料,经选择性沉淀制备含少量 Al和 Ti的 FePO ?xH O,并 4 5 12 4 2 以其为前驱体制备了 Al?Ti掺杂的 LiFePO 。 该 LiFePO 在 1C和 2C倍率下的首次放电比容量分别达 151.3和 140.1? 4 4? mA?h/g,循环? 100?次之后容量无衰减。该方法也可用于钛白粉副产品硫酸亚铁的回收利用,制备性能优异的? LiFePO 。 4 关键词:钛铁矿;二氧化钛;正极材料;负极材料;磷酸铁锂;钛酸锂 中图分类号:TM912.9? 文献标志码:A? Preparation?of?titanium?dioxide,?lithium?titanium?oxide?and? lithium?iron?phosphate?from?ilmenite? LI Xin?hai,?WU?Ling,?WANG?Zhi?xing,?GUO Hua?jun,?PENG Wen?jie,?WU?Fei?xiang? School?of?Metallurgical?Science?and?Engineering,?Central?South?University,?Changsha?410083,?China? Abstract:?Titanium? hydrolysate?and? iron?rich?lixivium? were? obtained? from? the?ilmenite? by?mechanical?activation? and? hydrochloric?acid?leaching.?By?using?H O as?a?coordination?agent,?titanium?was?leached?from?the?titanium?slag?and?a? 2 2? coordination? lixivium? was? obtainedA? nano?sized? platelike? peroxo?titania? compound? was? prepared? by? heating? the? coordination?lixivium.?The?peroxo?titania?compound?was?washed?and?sintered,?then?a?nano?sized?platelike?TiO 99.31%,? 2? mass?fraction?was?obtained.?Li Ti O was?synthesized?by?sintering?the?mixture?of?peroxo?titania?compound?and?Li CO ,? 4 5 12? 2 3 the? sample? shows? a? good? electrochemical? performance? as? an? anode? material? for? the?lithium?ion? batteriesA? selective? precipitation? method? was? used? to? synthesize? FePO ?xH O? precursor? from? the? iron?rich? lixiviumThe? Ti?Al? doped? 4 2 LiFePO was?prepared?using?the?FePO ?xH O?as?the?starting?material.?The?as?prepared?LiFePO exhibits?a?first?discharge? 4? 4 2 4? capacity?o