化学法合成Zn(OH)2及其ZnO的相转变研究论文（毕业学术论文设计）.docVIP

化学法合成Zn(OH)2及其ZnO的相转变研究 学 科： 材料物理与化学 作 者： (签名) 指导教师： (签名) 摘要 本研究采用化学法合成工艺，以乙酸锌、氨水为出发原料，通过改变氨/锌比，研究了影响氧化锌的主要及其作用规律在此基础上，通过改变氧化锌氧化锌。实验表明：(1) Zn(OH)2的主要因素有反应温度、浓度、氨/锌比。在本次研究条件下，随着反应温度的升高，氢氧化锌棱塔尺寸变大；氨/锌比过小，乙酸锌和氨水的浓度过大，都无法得到具有良好结晶的氢氧化锌棱塔；反应温度为25℃，氨/锌比为2.58:1，乙酸锌为9.1×10-2mol*L-1及氨水为2.94×10-1mol*L-1的浓度下，可以得到具有良好结晶的氢氧化锌棱塔。(2) Zn(OH)2棱塔向ZnO相转变受到反应温度、反应时间、pH值的影响。在本研究条件下，在中性水体系条件下，相转变温度约为100℃，完成相转变的反应时间约为2h左右，另外，反应环境的pH显著影响这一相转变过程，使用氢氧化钾调节反应环境pH值，可以降低氢氧化锌棱塔向氧化锌相转变的温度至80℃附近。 关键词：氧化锌；氧化锌；KOH Chemical synthesis of zinc hydroxide morphology and transition to zinc oxide research Specialty: Material Physics Chemistry Undergaduate: Zhao Yan (Signature): Supervisor : Zhang Weihua (Signature): Abstract Using the chemical synthesis process and acetic zinc, ammonia as raw material, we studied the main factors and rules on the influence of zinc hydroxide arris tower microstructure by changing the mole ratio of ammonia and acetic zinc, reaction temperature, concentration, separation times and separation method; On this basis, studied the main factors on the influence of zinc hydroxide edge column to the zinc oxide phase transition through changing the reaction temperature, reaction time, response to environmental pH, discussion of zinc oxide to zinc oxide phase transition of suitable process conditions. The experimental results demonstrate that: (1) The true impact of zinc hydroxide arris tower chemical synthesis factors are reaction temperature, concentration, the mole ratio of ammonia and acetic zinc . In the present study condition, with the increase of reaction temperature, zinc hydroxide arris tower size; the mole ratio of ammonia and acetic zinc is too small, zinc acetate and ammonia concentration is too large, can get good crystallization of zinc hydroxide arris tower; the reaction temperature is 25℃, the mole ratio of ammonia and acetic zinc is 2.58:1, zinc acetate for 9.1x10-2mol*L-1 and ammonia as 2.94×10-1mol*L-1 concentrations, can be obtained with go