《电导法测定弱电解质电离常数及难溶盐溶解度》课件.pptVIP

Content Purposes and Demands Principle Apparatus and Reagent procedure Data Records and Processing Questions Attentions Demonstrated Purposes and Demands 1.? To determine the ionization constant of acetic acid. 2. To determine the solubility of calcium sulphate. 3. Master the operation of conductivity detector. Principle 1）Determination of weak electrolyte ionization constant. At certain temperature, the equilibrium of acetic acid ionization in water can be written as follow HAc = H+ + Ac－ Initial c 0 0 eg c(1-α) cα cα K —— conductivity (s/cm or ms/cm orμs/cm). It can be determined through experiment. C —— concentration (mol?L-1 or N ? L－1) 2）Determination of hardly dissolved salt’s solubility Kc = Ksolution – KH2O Ksolution —— conductivity of solution KH2O —— conductivity of water Apparatus and Reagent Conductivity detector 1 Super thermostatic trough 1 Conical flask （250ml） 2 Conical flask （50ml） 3 Pipette (20ml) 2 Beaker (100ml) 1 0.1000M HAc solution CaSO4(A.R) Procedure 1）Determination of weak electrolyte ionization constant 1. Regulate the temperature of thermostatic trough at 25℃±0.1℃. Put two conical flasks one of which is filled with 120-130ml conductive water and another with 40ml HAc(0.1M) into thermostatic trough, and maintain the temperature at this level for 20 min. 2. Clean a platinum black electrode with distilled water and blotted it up by the use of filter paper (don’t touch platinum -black). Put the electrode into the conical flask filled with 40ml HAc and detect the conductivity. Remove l of HAc solution and complement with 20ml conductive water that has been kept temperature constant, shaking up. After temperature is kept constant for 5 min, determine the conductivity of the solution above. Repeat the same dilution procedure to confect other five HAc solution of different con