（毕业学术论文设计）-外文翻译--二氧化钛胶粒嵌入超细层状钛酸盐制备金红石型氧化钛纳米纤维(中英文混合版).docVIP

J. Yang et al. / Materials Letters 61 (2007) 1855-1858 翻译者：向兴龙 第 PAGE 1 / NUMPAGES 11页 原 作 者 ： Juan Yang（杨娟） , Qinqin Liu（刘芹芹） , Xiujuan Sun（孙秀娟） Preparation of rutile TiO2 nanofibers by TiO2 sol intercalation of ultrafine layered titanate 二氧化钛胶粒嵌入超细层状钛酸盐制备金红石型氧化钛纳米纤维 Juan Yang（杨娟）, Qinqin Liu（刘芹芹）, Xiujuan Sun（孙秀娟） 江苏大学材料科学与工程学院，江苏镇江，邮编：212013 2006五月17日收到； 2006年7月23日接受； 2006年8月15日开始在线使用 Abstract To prepare TiO2 intercalated tetratitanate, TiO2 solution and ultrafine layered titanate K2Ti4O9 obtained via solid-state reaction by using nanometer-sized TiO2 as raw material were used as guest and host materials respectively. The structure and morphology of the resulting samples were characterized by XRD and TEM experiments. It was found that during the intercalation process, the interlayer distance was expanded step-by-step and the interlayer structure of titanate might be destroyed and degraded to slits by prolonging the solution intercalation time. Rutile TiO2 nanofibers with the average size of 5×50 nm were obtained at room temperature while the duration time was prolonged to 72 h. ? 2006 Elsevier B.V. All rights reserved. 摘要：为了制备二氧化钛嵌入钛酸盐（tetratitanate）材料，用二氧化钛溶胶和超细层状K2Ti4O9分别作为主体和辅体原料进行固相反应得到纳米二氧化钛。对试样的结构和形貌进行了XRD和TEM表征。研究结果表明，嵌入过程中，延长嵌入时间，层间距离会逐步增大，钛酸盐夹层结构被破坏然后微裂纹空隙中被微小粒子嵌入。室温下持续72小时可得到平均尺寸约为5×50nm的金红石型TiO2纳米纤维。 ? 2006 Elsevier B.V保留所有权利。 Keywords: Rutile TiO2 nanofiber; Ultrafine layered titanate; Sol intercalation 关键词：金红石纳米纤维；超细分层钛酸盐；溶胶插入法 1. Introduction Recently, the pillaring of sol particles into layered inorganic solids has received considerable attention, since this provides a useful strategy to create novel porous materials and inorganic/organic nanocomposites [1-3]. It has been reported that the introduction of small semiconducting particles of CdS-ZnS, Fe2O3 and TiO2 into the interlayer of layered materials such as montmorillonite, smectite clays, layered niobate and layered titanate gives rise to a remarkable enhancement of their photocat