化学发光测定奶粉中三聚氰胺（论文）.doc

化学发光测定奶粉中的三聚氰胺 摘 要：化学发光是一种特殊的发光现象，产生于化学反应过程中。反应产物在反应中受激发处于激发态，当从激发态跃迁回基态时，以光辐射的形式释放出一定的能量。发光强度与被测物的浓度有正比关系，借此可进行定量分析。化学发光有几种类型，一类是低温化学发光，通常在常温条件下进行，另一类发光反应发生在某些物质的光解过程中：化学发光分析可用于测定微时金属元素、大气污染监测等方面。三聚氰胺，俗称密胺、蛋白精，IUPAC命名为“1,3,5-三嗪-2,4,6-三胺”，是一种三嗪类含氮杂环有机化合物，被用作化工原料。它是白色 HYPERLINK /view/1539407.htm \t _blank 单斜晶体，几乎无味，微溶于水（3.1g/L常温），可溶于甲醇、甲醛、乙酸、热乙二醇、甘油、吡啶等，不溶于 HYPERLINK /view/52518.htm \t _blank 丙酮、醚类、对身体有害，不可用于食品加工或食品添加物。 关键词：三聚氰胺；流动注射 - 化学发光；食品 Determination of Melamine in Milk Powder by Flow Injection-Chemiluminescence Combined withSolid Phase Extraction MaoWenHua (Chongqing Technology and Business University of commerce environment and biological engineering college · chongqing 400067) Abstract ：Chemiluminescence is a luminous phenomenon special, produced in the chemical reaction process. The reaction product is excited in the excited states in the reaction, when from the excited state transition back to the ground state, the light radiation is released in the form of a certain energy. The luminous intensity and the concentration of analyte is proportional to the relationship, which can make quantitative analysis. Chemiluminescence has several types, one is the low temperature chemical luminescence, usually under the condition of normal temperature, another light-emitting reactions occurring in the photolysis process certain substances: chemiluminescence analysis can be used for the determination of micro metal elements, atmospheric pollution monitoring etc.. It is white monoclinic crystal, almost tasteless, slightly soluble in water (3.1g\/L at room temperature), soluble in methanol, formaldehyde, acetic acid, ethylene glycol, glycerol, hot pyridine, insoluble in acetone, ether, harmful to the body, can not be used for food or food additives. Key words：melamine；flow injection-chemiluminescence； food 一、三聚氰胺的简述 三聚氰胺，简称三胺，又称氰脲三酰胺、三聚氰酰胺、蜜胺，是一种三嗪类含氮杂环有机化合物，化学名称为 2,4,6- 三胺基 -1,3,5- 三嗪(2,4,6-triamino-1,3,5-triazine)或 1,3,5- 三嗪 -2,4,6- 三胺(1,3,5-triazine-2,4,6-triamino)，分