离子液体应用术进展4.pptVIP

离子液体应用技术进展Ionic Liquid Application Technology Progress 王少君 大连工业大学 一、离子液体的多样化Diversified range of applications of ionic liquids(ILs) Main cations and anions described in literature Properties of ionic liquids Melting point; Volatility; Non flammability; Thermal and chemical stability; Conductivity and electrochemical window; The challenge here is still to design ILs with wide electrochemical window along with good electrical conductivity. Density; Viscosity; The design of less viscous ILs is still a challenge for many applications. Polarity; Toxicity and biodegradability; Surface tension. For industrial implementation, some IL properties must be investigated under real process conditions. A widening range of ionic liquids availableILs with targeted properties (decrease viscosity and density). New methimazole based Ils Examples of ILs with targeted functions Cost-effective ILs These Ils can contain a weakly basic anion and a cation formed from a tertiary amine and an exchangeable proton.‘‘Bio’’ ILs Protic ILs synthesised by direct protonation (X = [NTf2], [CF3SO3], [CF3CO2], [CH3SO3], [HCOO], [HSO4], [H2PO3]). The case of protic bases (such as dialkylamines) has also been studied ILs based dendrimer polymers base (Multi)-functional ionic liquidsAcid and basic ILs Mono-charged diamine based ILs which incorporate Lewis basicity site (DABCO type) on the cation with both thermal stability and low meltingpoint can be obtained when associated with [NTf2] anion. Chiral Ils Highly ordered mesoporous functional organosilicas incorporating chiral camphorsulfon- amide entities were synthesised by a hydrolysis–polycondensation involving chiral imidazolium precursors and tetraethoxysilane (TEOS) Switchable-polarity solvents (SPS) ILs at the frontier between organic and inorganic materials a.Inorganic cations. b. Deep eutectic solvents (DES). Recently, some deep eutectic mixtures with properties similar to those of ILs, have been described. These