神华煤灰成分因子研究分析及聚类研究分析.docVIP

PAGE PAGE 6 动力煤煤灰成分的因子分析及聚类分析? ?收稿日期：；接受日期： 作者简介：刘青山（1980-）、男、山东、工程师、硕士，从事矿产品取制样及数理统计应用研究。E-mail： HYPERLINK "mailto:smilldaily@; " smilldaily@。 刘青山，靳宏，王素梅，臧世阳，孙世明，王兆瑞，安鹏生 （天津出入境检验检疫局化矿金检测中心，天津 300457） 摘要：应用多元统计中的因子分析法对46批动力煤煤灰成分SiO2、A12O3、Fe2O3、CaO、MgO、Na2O、TiO2进行系统综合分析；从变量的相关矩阵出发，通过对煤灰成分的浓缩，提炼出新的起主导作用的三个独立因子，揭示了煤灰成分三个主因子的分布特征，分析了各煤灰成分在主因子上的载荷；根据三维空间载荷分布图分成的四个群，对每个群内的煤灰成分特性及相互关系进行了系统的解释。利用多元统计中的聚类分析法根据煤灰成分因子分析结果对动力煤进行分类，结果显示：46批动力煤根据煤灰成分特性分成四类，其中第一类共有7批、第二类共有6批、第三类共有13批、第四类共有20批。 关键词：煤灰成分；因子分析；灰熔融性；聚类分析 Factor Analysis and Cluster Analysis on Ash Compositions of Steam Coal LIU Qing-shan, JIN Hong,WANG Su-mei, ZANG Shi-yang,SUN Shi-ming, WANG Zhao-rui, AN Peng-sheng (Chemicals, Minerals & Materials Inspection Center of Tianjin Entry-Exit Inspection and Quarantine Bureau, Tianjin 300457, China) Abstract: Ash compositions (SiO2、A12O3、Fe2O3、CaO、MgO、Na2O、TiO2) of steam coal were studied comprehensively by the factor analysis method; Based on correlation matrix of ash composition variables, the three factors were extracted from them. The distribution characteristics of three factors were explored and the loading of ash composition on factors were analyzed; Ash composition variables were divided into four groups, in which, the characters and relations of ash composition were explained systematically. The 46 batches of steam coal were classified into four categories by the cluster analysis method on the results of factor analysis, and the first categories including 7 batches, the second categories including 6 batches, the third categories including 13 batches, the last categories including 20batches. Key words: ash composition; factor analysis; ash melts; cluster analysis 煤灰的熔融性是指煤灰受热时由固态向液态逐渐转化的特性，煤灰的熔融性是动力用煤高温特性的重要测定项目之一。由于煤灰不是一个纯净物，它没有严格意义的熔点，衡量其熔融过程的温度变化，通常用三个特征温度：即变形温度（DT）、软化温度（ST）、流动温度（FT）。这三个温度代表了煤灰在熔融过程中固相减少，液相渐多的三点，在工业上多用软化温度作为熔融性指标，称为灰熔点。 煤灰熔融温度的高低取决于煤灰的组成及含量。煤灰的化学组成十分复杂，由化学分析结果表明，煤灰一般由SiO2 ，A12O3，Fe2O3 ，CaO，MgO，Na2O，K2O，TiO2等组分构成，这些氧化物在纯净态下的熔点很高。然而，煤中矿物