锂离子电池正极材料高镍lini__省略__co_xmn_yo_2研究进展_刘嘉铭.pdf

第 44 卷第 7 期 硅 酸 盐 学 报 Vol. 44 ，No. 7 2 0 1 6 年 7 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY July ，2016 DOI ：10.14062/j.issn.0454-5648.2016.07.03 综 合 评 述 锂离子电池正极材料高镍LiNi Co Mn O 研究进展 1−x−y x y 2 刘嘉铭，张英杰，董 鹏，李 雪，夏书标 ( 昆明理工大学冶金与能源工程学院，昆明 650093) 摘 要：高镍含量三元层状材料 LiNi Co Mn O (NCM)凭借比容量高、成本较低和安全性优良等优势，成为研究的热点， 1−x−y x y 2 被认为是极具应用前景的锂离子动力电池正极材料。综述了高镍 NCM 材料的晶体电子结构特征以及镍含量变化对性能的影 响，介绍了国内外主要的制备方法和掺杂和包覆改性的机理和特性，并展望了高镍NCM 材料未来的应用和发展方向。 关键词：锂离子电池；正极材料；镍钴锰氧化物；综述 中图分类号：O484 文献标志码：A 文章编号：0454–5648(2016)07–0931–11 网络出版时间：2016–05–30 10:27:26 网络出版地址：/kcms/detail/11.2310.TQ1027.017.html Progress of Nickel–rich LiNi Co Mn O as Cathode Materials for Lithium Ion Battery 1−x−y x y 2 LIU Jiaming , ZHANG Yingjie, DONG Peng , LI Xue , XIA Shubiao (Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China) Abstract: Due to their advantages of high specific capacity, low cost and high safety, nickel–rich layered metal oxide materials LiNi Co Mn O (NCM) are believed to be a candidate of the potential cathode materials for lithium ion power battery, and have 1−x−y x y 2 become a research hotspot. The impact of crystal structure, electronic structure, and nickel content on the electrochemical performance of nickel–rich NCM were summarized, the main synthesis methods at home and abroad, the mechanism and characteristics of c