二氧化氯对油田回注水的杀菌效果及工程应用-环境科学与工程专业论文.docxVIP

Classified Index：X791 U.D.C.: 623.8 A Dissertation for the Degree of M. Eng. THE BACTERICIDAL EFFECT OF CHLORINE DIOXIDE IN THE OILFIELD INJECTION WATER TREATMENT AND ENGINEERING APPLICATION Candidate：Wu Candidate： Wu Mingsong Supervisor： Prof. Huang Jun Academic Degree Applied for： Master of Engin Specialty： Environmental S Affiliation: School of Muni. Date of Defence： July, 2007 Degree-conferring-institution: Harbin Institute ci. and Eng. Env. Eng. of Technology 摘要 在石油工业中，石油开采过程的需水用水量是极为巨大的。由于我国大 部分油田采用注水采油工艺，而在回注过程中主要由微生物引起的腐蚀堵塞 问题严重，因此采用杀菌效果明显的药剂一直是石油回注水水处理研究的热 点。 本文就应用二氧化氯以大港油田枣一回注水站的石油回注水为对象开展 了全面深入的杀菌、腐蚀研究，并成功的进行了二氧化氯的生产性试验研 究。同时提出了一种新的以酸性绿 B 为褪色剂的水中二氧化氯浓度的测定 方法。 研究结果表明：酸性绿B法是一种简便有效的测定水中二氧化氯的方 法，具有操作简单、所需药品少、颜色稳定、灵敏快速、结果准确度和精密 度高、抗干扰性好的特点。二氧化氯是有效的杀菌剂，在投加 3.0mg/L时， 对硫酸盐还原菌、腐生菌和铁细菌的杀菌率即可达标，5.0mg/L时，杀菌率 均可达到或者极接近 100%。反应时间越长，杀菌率越高，反应 10min后， 细菌指标可达到注水标准的要求。温度与pH对反应结果影响不大，在 60℃ 左右时可达到最好的杀菌效果，在pH为 7～9 的范围内杀菌率可达到 90％以 上。同时投加ClO2之后，Fe2-和S2-可以容易地被ClO2除去，回注水管道的腐 蚀情况也得到了明显改善。 生产性试验研究表明：应用二氧化氯对石油回注水进行杀菌，投加 3.0mg/L的二氧化氯就可以很好的抑制水样中菌类的滋生，投加 5.0mg/L即 可保证持续杀灭管道中细菌，Fe2+和S2-的去除率均相当好，管道的腐蚀情况 也得到了很好的改善。经过经济技术分析，应用二氧化氯杀菌可以每年节约 成本 49.2 万元，具有很好的经济效益。 关键词 二氧化氯；测定方法；石油回注水；杀菌；腐蚀 Abstract Water injection for oil exploitation is adopted widely in the petroleum exploitation in our country, and it needs a great deal of water every year. However, Corrosion and plugging caused by the microorganism in the injection water is very severe. The effective medicaments have been popularly studied and applied to the oil injection water for reducing the issues. The sterilization and anticorrosion in the rejection water from Zaoyi injection station in Dagang oil field was thoroughly studied, where chlorine dioxide medicament was applied. And then full-large test was completed successfully. A new method of determination ClO2 in the water is also provided, in which the fading agent is the AGB. This study show that using AGB to determinate ClO2 is simple and effective; it requires fewer drugs, b