常见的石油类污染场地调查和修复以及.ppt

* XX涂料厂地块在上世纪50年代曾建有农药厂，80年代起改为涂料厂，部分土壤已被污染。根据中科院生态环境研究中心此前对XX涂料厂地块进行的评价，确定污染物为“六六六”和DDT，被污染土壤约为14万立方米，一些市民担心受污染土壤未来可能有害住户健康。 万科对7.9公顷土壤进行100多个样点采集，届时将采集800多个样品 ;考虑到治污成本，该地块出让的价格相对较低，万科拿地楼面价仅合1700元/平方米，而附近房地产开发项目的销售均价达9000元/平方米。 * 该场地具有66年的大型氯碱生产的历史 * Complicated contamination issues and extremely remediation costs Contamination presents several challenges Contaminant movement along bedding planes, joints, fractures Fluid diffusion into the matrix NAPL flow very complex Capillarity, gravity, viscosity considerations Downhole geophysical methods Televiewers (optical and acoustic) Coring methods Groundwater flow modeling Pumping tests Monitoring wells Tracer testing Flowmeter testing * Heavier than water; low solubility; pooling issues Often difficult to find source Traditional soil and groundwater sampling is “hit-or-miss” Geophysical methods Innovative characterization technologies Membrane interface probe Laser-induced fluorescence * Vapor samples collected directly from subsurface Temporary or permanent sampling wells Replacing modeling and passive indoor sampling Leak detection methods Common compounds applied at connections Positive pressure inert gas environment (“shroud”) * T,ECD（氯代物）, FID (直链化合物），PID（多环芳），ROP，EC（地质） * Becomes prohibitive with larger, complex sites Groundwater Double-handling and characterization Backfilling/staging Surface obstructions Tipping fees keep increasing Regulators increasingly looking for alternatives Emissions, space * * 450 SCFM Max. (25 hp blower) 29” Hg. Max. Vacuum 50 gal/min. Water Extraction Max. Water Treatment Process (Pat. Pending) 400,000 BTU/hr. Excess Air Burner 99+% DRE (LPG or Nat. Gas Supl. Fuel) Requires No Hookups to Site Utilities * * * * * Saturated zone (soil and groundwater) remediation technology Air injected into subsurface; rises due to buoyancy (often with SVE system) Effective for variety of phases (gas, sorbed, dissolved, free-phase) Induces volatilization, advection, diffusion, desorption, and