《MPUF树脂胶固化动力学研究》-毕业学术论文设计.docVIP

MPUF树 脂 胶 固 化 动 力 学 研 究 摘　要: 　用傅立叶红外光谱( FTIR)跟踪研究了苯酚-三聚氰胺-尿素-甲醛树脂( MPUF )的反应,并结合示差扫描量热仪(DSC) 对MPUF固化反应过程进行了分析, 并用Kissinger 和Ozawa 方法分别求得固化反应的表观活化能ΔE 为57.801KJ/mol -1 ，55.329KJ/mol -1 ，52.804KJ/mol -1 ; 根据Crane 理论计算得到该体系的固化反应级数n =0.6 , 为MPUF树脂胶的固化工艺确定提供理论依据。 关键词: DSC 法; MPUF; 苯酚-三聚氰胺-尿素-甲醛树脂; 固化反应动力学,傅立叶红外光谱 摘要：运用红外光谱分析竹材液化胶固化温度及固化机理；采用DSC方法探讨了竹材液化胶酚醛物质的量的比（F/P）为1.3、1.5、1.8的竹粉液化胶的固化反应过程。在25-300℃的温度范围内，以不同升温速率（5、15、20和30℃/Min）进行固化动力学分析。运用Kissinger和Ozawa法进行动力学研究，得到其活化能。结果表明：两种方法计算得到活化能的大小顺序是一致的。高物质的量比竹材液化胶在固化过程中具有的活化能比低物质的量的竹材液化胶的要低，这就意味着高物质的量的比竹材液化胶固化时需要较少的热量。因此，竹材液化胶的F/P的物质的量比越高，固化反应的活化能就越低。随着升温速率提高，该种树脂的起始固化温度Ti，峰顶固化温度Tp，终了固化温度Tf都有提高，同时固化时间缩短。 Study on curing reaction kinetics of Phenol-melamine-urea-formaldehyde resin Abstract :The reaction between the p repolymer of Phenol-melamine-urea-formaldehyde resin ( MPUF) was studied with FTIR and DSC.The curing reaction process of MPUF was studied by DSC and carefully analyzed. Based on the Kissinger method and Ozawa method , the ap2parent activation energy (ΔE ) was got 58127 and 64193 kJPmol respectively. The reaction order n = 0185 cal2culated according to Crane theory , and thesedata could be used for the curing system in the curing processing. Key words : DSC; MPUF ; Phenol-melamine-urea-formaldehyde resin ; curing reaction kinetics,Fourier Transform Infrared Spectrography (FT-IR) 目 录 1 引言·····································································（3） 1.1 选题的背景和意义 ····················································（3） 1.2 国内外研究现状和发展趋势·············································（3） 1.3 研究的基本内容和拟解决的主要问题·····································（4） 2 研究方法································································· （5） 2.1 树脂合成···························································· （5） 2.1.1 原料用量比为················································· （5） 2.1.2 实验仪器····················································· （5） 2.2 工艺方法·······················································