NH3-SCR反应的原位红外分析.docxVIP

原位红外数据分析 1. In situ DRIFTS of NH3 adsorption 表1. NH3吸附的原位红外数据分析 催化剂 峰位波数值（cm-1） 解释 参考文献 Ce5Cu5-OMC， Ce0Cu10-OMC 1403 the symmetrical bending vibration of NH4 J. Chen, et al. J. Colloid Inter. Sci. 456(2015)66-75. 1630，1120，1250 the coordinated NH3 on the Lewis-acid sites 1510 an amide (-NH2-) species Mn(0.4)/TiO2 1598,1210 coordinated NH3 on Lewis acid sites Z. Wu, et al. Environ. Sci. Technol. 41(2007)5812-5817 1443, 1850-1640 NH4+ 3349,3245, 3149 NH stretching ~3700(负峰) surface O-H stretching 966, 1230 weakly adsorbed NH3 or gas-phase NH3 Fe(0.1)-Mn(0.4)/TiO2 1170 the coordinated NH3 on Fe2O3 Z. Wu, et al. Environ. Sci. Technol. 41(2007)5812-5817 3700 the surface O-H stretching, acidic O-H group FeaMn1-aTiOx 1805 physisorbed NH3 F. Liu, et al. Appl. Catal. B: Environ. 93(2009)194-204 1676, 1458 NH4+ 3020, 2806 N–H stretching vibration modes of NH 3732, 3676(负峰) O–H stretching vibration mode due to the interaction of surface hydroxyls with NH3 1344（负峰） The coverage of residual sulfate species 1603, 1192 coordinated NH3 bound to Lewis acid sites 3365, 3253, 3160 N–H stretching vibration modes of coordinated NH3 Mn/Ti MnV/Ti CeMn/Ti 1594 σas model of NH3 coordinated to Lewis acid sites X. Wu, et al. J. Rare Earth. 29(2011)64-68. 1445 σas model of NH3 coordinated to Lewis acid sites 1165 Lewis acid sites Mn/TiO2 1680, 1460, 1430 The symmetric or asymmetric bending vibration of NH formatting on Brosted acid sites J. Li, et al. Catal. Commun. 8(2007)1896-1900. 1595, 1195, 1165 symmetric and asymmetric bending vibration of N–H in NH3 coordinated to Lewis acid sites 1530 amide (NH2) species Mn0.4Ce 1190, 1300, 1560, 1620 Lewis acid sites Z. Ma, et al. Catal. Commun. 69(2015)188-192. 1430, 1670 vibration of NH4 W0.1Mn0.4Ce 990 W=O bonds act as acid sites for NH3 adsorption V2O5/CeTiOx V2O5/CeO2 1594,1174, 1284 asymmetric and symmetric bending vibrations of the N?H bonds in NH3 coordinately linked to Lewis acid sites Z. Lian, et al. Ind. Eng. Chem. Res. 53, (2014)19506