清华大学有化学李艳梅老师课件第5章.pptVIP

共四个异构体： R R S S R S R S 3 3 3 3 3C 为非不对称碳 均有旋光性 互为对映异构体 3C 为不对称碳 均无旋光性 为内消旋体 互为非对映异构体 假不对称碳 Optical Stereomer C3 is symmetric Not optical Meso C3 is asymmetric 5.5.1 Cyclopropane, cyclobutane, and cyclopentane 5.5.2 derivatives of Cyclohexane 5.5 Cyclic compound 关键：平面分析 构象分析 5.5.1 Cyclopropane, cyclobutane, and cyclopentane 1, Cyclopropane A σ σ A A A A A A Trans- Cis- A B B A A B B A Cis- Trans- A A A A A A 2, Cyclobutane 3, Cyclopentane Learn on your own 5.5.2 Derivatives of Cyclohexane 顺-1,2-二取代 平面分析： 构象分析： Rotation Conformation transition (i)’ (i)’ (i)’’ (i)’’’ Rotation