碳化还原法制备纳米化铬粉末.doc

PAGE PAGE 1 2010届毕业生 毕业论文 题 目: 碳化还原法制备纳米碳化铬粉末 院系名称：材料科学与工程 专业班级： 材料F0605 学生姓名： 学 号： 指导教师： 教师职称： 2010年 摘要 过渡金属碳化物具有较高的熔点、硬度和高温强度，这些材料同样显示良好的电导率和热导率。这些优异的性能确保了它们在冶金、电子、催化剂和高温涂层材料等方面的广泛应用。 现在，各种各样合成碳化铬粉末的方法已经被研究，包括直接元素反应法、机械合金化法、程序升温反应法和气相还原碳化法。但是，这些方法在工业应用中受到了限制，主要由于团聚问题、较宽的粒径分布、低产量、复杂的监控和昂贵的成本。 本实验课题采用纳米碳黑和纳米氧化铬为原料，用碳化还原法制造纳米铬，分别在不同的C含量（26%，28%），不同的烧成温度（900℃，1000℃， 通过实验得出以下结论：在C含量为28%，烧成温度为1100℃，保温时间为90min时，生成物不含其它杂质相，为单一的Cr3C2， 关键词：碳化铬，碳化还原法，纳米氧化物，XRD Title：Preparation of nano carbon reduction chromium carbide powder Abstract Transition metal carbides has a high melting point, hardness and high temperature strength, these materials also show good electrical conductivity and thermal conductivity. The excellent performance to ensure that their metallurgy, electronics, catalysts and high-temperature coating materials such as extensive use of Now, the various chromium carbide powder synthesis methods have been studied, including direct element reaction, mechanical alloying, temperature-programmed reaction and carbonation gas reduction law. However, these methods in industrial applications has been limited, mainly due to reunion, a wide size distribution, low yield, complicated and expensive monitoring costs. In this study, subjects using nano-carbon black and nano-chromium oxide as raw materials, manufacture nano-carbon chromium reduction method At different C content (26%, 28%), different sintering temperature (900 ℃, 1000 ℃, 1100 The experiment shows the following conclusions: the C content was 28%, sintering temperature is 1100 ℃, holding time was 90min, the resultant free of other impurity phase, various properties of chromium carbide nano the most close to ideal Keywords：Chromium carbide, carbon reduction, nano-oxides, XRD 目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc263467133 1 绪论 PAGEREF _Toc263467133 \h 1 HYPERLINK \l _Toc263467134