在Ni-Zr-Ti-Nb体系中具有高非晶形成能力的不含类金属元素的Ni基非晶.DOC

Ni-Zr-Ti-Nb-M（M=Sn,Bi）块体非晶合金的形成及其磁性能研究 郑许，杨元政，李青，谢致薇 （广东工业大学 材料与能源学院，广东 广州 510006） 摘要：从共晶点、混合热、原子尺寸差和微合金化出发，设计出了Ni-Zr-Ti-Nb体系具有较高非晶形成能力的Ni基合金成分，用铜模吸铸法制备了直径2mm的块体非晶合金，用X射线衍射、差热扫描量热仪、振动样品磁强计检测了样品的组织结构、热稳定性和磁学性能。结果表明：微量Sn的添加提高合金非晶形成能力，可制备出直径2mm的棒状完全非晶试样。而Bi不利于提高Ni-Zr-Ti-Nb体系合金的非晶形成能力。此外，微量Sn能使饱和磁感应强度稍有提高。 关键词：镍基块体非晶合金；非晶形成能力；软磁性能 中图分类号：TG139.8 Glass Formation and Magnetic Properties Of Ni-Zr-Ti-Nb-M(M=Sn,Bi) Bulk Amorphous Alloy ZHENG Xu, YANG Yuanzheng, LI Qing, XIE Zhiwei, CHEN Xianchao （Faculty of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China） Abstract:From the view point of eutectic point, heat of mixing, atomic size difference and microalloying, Ni-Zr-Ti-Nb-M（M=Sn,Bi）alloys with high glass forming ability were designed.Bulk metallic glassy rods with a diameter of 2mm were obtained by copper-mold vacuum suction casting. The microstructure, thermal stability and magnetic was examined by X-ray diffraction, differential scanning calorimetry and vibrating sample magnetometer. Respectively, The results showed that: microalloy element Sn can improve glass forming ability (GFA) of the Ni–Zr-Ti-Nb BMG system. Adding small amount of Bi is not beneficial to the GFA of this alloy system. On the other hand, Addition of Sn slightly enhances the saturation magnetization (Ms) of the alloy system. Key words: Ni-based bulk amorphous alloy；glass forming ability；soft magnetic property Ni基非晶合金表现出高热稳定性、高断裂强度、高硬度、高杨氏模量、强耐腐蚀性能 ADDIN EN.CITE ADDIN EN.CITE.DATA [1-3]。具有重要的潜在工程应用价值。目前已经可以制备出直径达5mm的棒状块体Ni基非晶合金 ADDIN EN.CITE ADDIN EN.CITE.DATA [4-5]，如Ni59Zr16Ti13Si2Sn3Nb7和Ni40Zr16.5Ti28.5Al10Cu5。在Ni基非晶成分设计方面，董闯等人提出了[MNi6Ta6]Ni3的原子团簇胶粘模型 ADDIN EN.CITE EndNoteCiteAuthorWang/AuthorYear2010/YearRecNum270/RecNumrecordrec-number270/rec-numberforeign-keyskey app=EN db-id=5a5wz0vxff2w2nef0w8xfpaae2xaf90dv92d270/key/foreign-keysref-type name=Journal Article17/ref-typecontributorsauthorsauthorWang, Yingmin/authorauthorWang, Qing/authorauthorZhao, Jijun/auth