《聚氨酯纳米CaCO3复合材料的冲蚀磨损性能研究论文》-毕业论文.docVIP

聚氨酯/纳米CaCO3复合材料的冲蚀磨损性能研究 材料科学与工程专业 学生：*** 指导老师：*** 摘 要 本文以甲苯－2、4－二异氰酸酯(TDI)、聚四氢呋喃醚二醇—1000(PTMG)、3,3－二氯－4,4－二苯基甲烷二胺(MOCA)为原料，采用预聚法合成浇注聚氨酯弹性体。选用纳米CaCO3粒子颗粒对聚氨酯弹性体进行强化，并且以微米Si3N4粒子作为对比组，对试样进行了力学性能和磨损性能的测试。 实验结果表明：纳米CaCO3粒子对纯聚氨酯弹性体的力学性能有一定的提高，并且纳米CaCO3粒子含量为1%时最佳；聚氨酯纳米CaCO3复合材料综合力学性能和磨损性能要比微米Si3N4复合材料好。 关键词：聚氨酯；纳米碳酸钙；力学性能；分散性；表面改性  Abstracts In this paper，polyurethane nano-composites were prepared prepolymer which was synthesized from diisocyanate(TDI), polytetrahydrofuran(PTMG), aromatic diamine(MOCA) firstly. Then the prepolymer was prepared by prepolymerization process，and the properties of polyurethane elastomer was strengthened by nano-CaCO3，The mechanical properties and erosion wear of the polyurethane nano-composite were tested and compared with the micron-Si3N4 composite. The results showed that the mechanical properties of polyurethane composite were enhanced by nano-CaCO3，and it had the best properties when the composite had 1% nano-CaCO3. The mechanical properties and erosion wear of PU/ nano-CaCO3 composite were better than PU/micron－Si3N4 composite. Keywords : Polyurethane, Nano-CaCO3, Mechanical Properties, Dispersity, Surface modification 目　录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc200691017 第1章 绪 论 PAGEREF _Toc200691017 \h 1 HYPERLINK \l _Toc200691018 1.1 引言 PAGEREF _Toc200691018 \h 1 HYPERLINK \l _Toc200691019 1.2 聚氨酯/纳米CaCO3复合材料发展趋势 1 HYPERLINK \l _Toc200691020 1.2.1 聚氨酯的发展趋势 1 HYPERLINK \l _Toc200691021 1.2.2 聚氨酯/纳米CaCO3复合材料发展趋势 2 HYPERLINK \l _Toc200691022 1.3 聚氨酯/纳米CaCO3复合材料研究现状 PAGEREF _Toc200691022 \h 3 HYPERLINK \l _Toc200691023 1.3.1 聚氨酯弹性体的结构特性与研究状态 PAGEREF _Toc200691023 \h 3 HYPERLINK \l _Toc200691024 1.3.2 纳米CaCO3特性与应用 PAGEREF _Toc200691024 \h 5 HYPERLINK \l _Toc200691025 1.3.3 聚氨酯/纳米CaCO3复合材料的研究现状 6 HYPERLINK \l _Toc200691026 1.4 聚氨酯/纳米CaCO3复合材料的制备研究 7 HYPERLINK \l _Toc200691027 1.4.1 聚氨酯的制备 7 HYPERLINK \l _Toc200691028 1.4.2 聚氨酯/纳米CaCO3复合材料的制备 8 HYPERLINK \l _Toc200691029 1.4.3 纳米粒子在基体中分散的制备 9 HYPERLINK \l _Toc2