The chemistry of graphene oxide英文版本.pdf

CRITICAL REVIEW /csr | Chemical Society Reviews The chemistry of graphene oxide Daniel R. Dreyer,a Sungjin Park,b Christopher W. Bielawski*a and Rodney S. Ruoff*b Received 7th October 2009 First published as an Advance Article on the web 3rd November 2009 DOI: 10.1039/b917103g The chemistry of graphene oxide is discussed in this critical review. Particular emphasis is directed toward the synthesis of graphene oxide, as well as its structure. Graphene oxide as a substrate for a variety of chemical transformations, including its reduction to graphene-like materials, is also discussed. This review will be of value to synthetic chemists interested in this emerging field of materials science, as well as those investigating applications of graphene who would find a more thorough treatment of the chemistry of graphene oxide useful in understanding the scope and limitations of current approaches which utilize this material (91 references). 1. Introduction applications (among others) through chemical functionalizations. We recommend that interested readers take note of recent During the last half decade, chemically modified graphene review papers about the physical properties of graphene,1 and (CMG) has been studied in the context of many applications, separately, chemical methods to produce CMGs via such as polymer composites, energy-related materials, sensors, established colloidal suspension methodologies.2 This critical ‘paper’-like materials, field-effect transistors (FET), and review will focus on the chemistry of graphene oxide, including biomedical applications, due to its excellent electrical, mechanical, its preparation, structure, and reac