《烧结制备聚晶氮化硼（PBN）的实验方法研究》-毕业论文设计.doc

PAGE 摘　　要 本文主要研究了使用立方氮化硼（cBN）和六方氮化硼（hBN）作为原料，加入适当的铝粉或者氮化铝粉作为烧结助剂来烧结制备聚晶氮化硼（PBN）的实验方法。将立方氮化硼和六方氮化硼分别与铝粉按照一定比例球磨混料均匀，在高温（约1000℃到1600℃）高压（约5.2GPa）环境下进行超高压通电烧结，制得聚晶氮化硼样品，并对样品进行了硬度检测，使用X射线衍射分析（XRD）和扫描电子显微镜（SEM）对样品的物相组成、显微结构和各组分元素的分布情况进行了初步的分析。通过实验结果得知： （1）使用六方氮化硼（hBN）作为原料烧结时，加入的铝粉作为烧结助剂的含量宜在20%以上；在实验的温度范围（1000℃到1600℃）内，温度越高越有利于反应进行。 （2）在烧结过程中，铝粉和氮化硼反应，生成了氮化铝，而生成的氮化铝填充在氮化硼晶粒的空隙之中，起到将晶粒整体粘连在一起的作用，最终形成完整的样品。 （3）使用未经真空处理的原料烧结的样品中，含有大量的微小气孔，影响了整体的致密度和性能。 关键词是为了文献标引工作从论文中选取出来、用以表示全文主题内容信息款目的单词或术语。如有可能，应尽量用《汉语主题词表》等词表提供的规范词。 关键词是为了文献标引工作从论文中选取出来、用以表示全文主题内容信息款目的单词或术语。如有可能，应尽量用《汉语主题词表》等词表提供的规范词。不用此信息时，删除此框。 关键词：聚晶氮化硼；烧结；高温高压 论文英文题目 Abstract This paper study the experiment method that using cBN and hBN as raw materials and adding aluminium powder or aluminum nitride powder in the right amounts as sintering aiding additives to sinter PBN. cBN, hBN and aluminium powder were grinded and well-proportioned mixed according to certain ratio. Under the high temperature( about 1000℃~1600℃) and high pressure(about 5.2GPa), the mixing powder turned into PBN with high pressure sintering. The phrase composition of PBN specimens was analyzed by X-ray diffraction and the microstructure of PBN was observed by SEM test while PBN also took a hardness test. After having the tests mentioned above done we could roughly analyzed the the distribution of different element contained in the constitute and made a conclusion from the result of the experiment: (1) When hBN is prepared as raw material to sinter PBN, the content of aluminium powder ,which is used as sintering aiding additives, should be no less than 20%; Within the range of experiment temperature(about 1000℃~1600℃), the higher the temperature rises, the easier the reaction goes. (2)During the sintering process, aluminium powder and BN reacted and generate AlN, which distributed over the site of BN crystal grain and connected the entire crystal grain together, producing the final complete sample. (3)Those specimens which were not process