磁性TiO2介观晶体的制备-生物材料与组织工程专业论文.docx

华 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract Mesocrystals are a kind of special nano-structured materials, which are built of crystallographically oriented nanoparticles.TiO2 mesocrystals are reported to possess high photocatalytic activity due to their high degree of crystallinity and large porosity. And to solve the problem on the callback of TiO2 after the light-catalyzed reaction, a route had been designed to endow the TiO2 mesocrystals with magnetic property, because of which mesocrystals can be easily separated from the reaction by external magnetic field. The main work is summarized as follows: Firstly, the co-precipitation and solve-thermal methods were adopted to prepare Fe3O4 nanoparticles with small and large size, and to increase the stability, these two kind of magnetic particles were coated with a thin SiO2 layer via the hydrolysis of TEOS. Secondly , the prepared Fe3O4@ SiO2 was introduced into the synthetic process of the NH4TiOF3 mesocrystals as seeds. Thirdly, the obtained Fe3O4@SiO2@NH4TiOF3 mesocrystals were converted to Fe3O4@SiO2@TiO2 through the hydrolysis in HBO3 solution or the sintering process. Lastly the photocatalytic activity of Fe3O4@ SiO2@TiO2 was evaluated by degrading the methylene blue solution. XRD, DLS and TEM results showed that the uniform magnetic nanoarticles with narrow size distribution had been successfully prepared and magnetic mesocrystals were obtained with a “round inside with square outside” structure, while the Fe3O4 coated with SiO2 served as the core and NH4TiOF3 mesocrystals as the shell. The magnetic TiO2 had good magnetic property and excellent photocatalytic activity . Key Words： titanium dioxide magnetic mesocrystals photocatalytic activity PAGE IV PAGE IV 目 录 摘 要 I HYPERLINK \l _bookmark0 Abstract II HYPERLINK \l _bookmark1 1 绪论 HYPERLINK \l _bookmark2 1.1 纳米 TiO2 的研究进展 (1) HYPERLINK \l _bookmark3 1.2 光催化技术原理 (4) HYPERLINK \l _bookmark4 1.3 磁性纳米颗粒的研究进展 (6) HYPERLINK \l _bookmark5 1.4 研究目的与意义 (