ZnCl2改性离子交换树脂的制备及其催化乙醇和乙酸酯化.pdf

2010 Chinese Journal of Catalysis Vol. 31 No. 6 文章编号: 0253-9837(2010)06-0666-05 DOI : 10.3724/SP.J.1088.2010.91142 研究论文: 666~670 ZnCl 改性离子交换树脂的制备及其催化乙醇和乙酸酯化反应性能 2 张 凤, 蒋晓原, 洪俊杰, 楼 辉, 郑小明 浙江大学理学院化学系催化研究所, 浙江杭州 310028 摘要：采用离子交换法制备了 ZnCl 改性的阳离子交换树脂催化剂, 考察了 ZnCl 浓度、离子交换时间和溶剂等对催化剂催化乙 2 2 酸和乙醇微波酯化反应性能的影响. 结果表明, 以去离子水为溶剂, 以 0.15%ZnCl2 溶液进行离子交换 30 h, 所得催化剂的性能较 好. 采用酸碱滴定法、紫外-可见光谱、傅里叶变换红外光谱、扫描电镜和 N2 吸附脱附等手段对催化剂进行了表征. 结果表明, 改 性后的催化剂 H+ 交换量约为原来的 1.5 倍, 表面酸强度增加; 树脂骨架结构变化不大; 紫外吸收峰发生蓝移, 吸收强度减小; 比 表面积略有减小; 催化剂在含水体系中表现出较高的催化活性, 且重复使用性能大大提高. 关键词：生物油; 离子交换树脂; 改性; 氯化锌; 微波酯化 中图分类号：O643 文献标识码：A Preparation of ZnCl -Modified Ion Exchange Resin and Its Catalytic Activity 2 for Esterification of Ethanol and Acetic Acid under Microwave * ZHANG Feng, JIANG Xiaoyuan , HONG Junjie, LOU Hui, ZHENG Xiaoming Institute of Catalysis, Department of Chemistry, College of Science, Zhejiang University, Hangzhou 310028, Zhejiang, China Abstract: An ion-exchange method was used to prepare a ZnCl2-modified ion exchange resin. Several factors such as impregnation liquid concentration, ion-exchange time, and solvent used in the preparation were examined. Optimal preparation conditions for the ZnCl2-modified ion exchange resin included the