离子强度对弱酸碱浓度平衡常数的影响.PDF

13 4 1998 8 ( ) 董 学 芝 ( 475001) ( ) , , , HB K c ; a K c ; H B K c K c b 2 a a 1 2 ( ) , : c c [ 1, 2] , K a K a ? ; 1 2 , , HAc K c ( ) [2] 1 , [ 1] a , [ 2] ; 2 , [ 2] , [ 1, 3~ 5] [ 2, 6] , ( ) 1. 对一元弱酸HB 的影响 HB : + - HB H + B K 0 : a 0 H+ B- K a = HB c K a : + - c [H ] [ B ] K a = [HB] i = [ i ], [ i] = , : i i i + - + - c [H ] [ B ] H B HB 0 HB K a = = = K a + - + - [HB] HB H B H B 0 c K a HB , HB 1, K a= + - H B 2 I 2 - lg i = 0512Zi - lg i =