导电聚合物复合膜修饰电极及其应用研究-物理化学专业论文.docx

西北师范大学 西北师范大学 硕士研究生毕业论文 导电聚合物复合膜修饰电极及其应用研究 研究生: 冯晓娟导 研究生: 冯晓娟 导 师: 胡中爱 专业: 物理化学 研究方向: 新能源材料 PAGE vi the composite film electrodes were investigated by electrochemical methods. The results of SEM and FTIR showed that the composite film had bi-layer structure with asymmetrical microstructure, where the inner layer (in contact with the conductive substrate) was conductive polyaniline with rich pores, while the outer layer(in contact with the electrolytic solution) was composed of non-conductive polysulfone with microporous structure. The data of electrochemical experiments indicated that the composite film electrodes had excellent electrocatalytic activity and reversibility towards the oxidation of hydroquinone (H2Q) and pyrocatechol (PC). The activity was so high that the two single electron transition processes for the oxidation of pyrocatechol were clearly distinguished. It was pointed out that the composite film electrodes had an electrochemically quantitative response for single solute and mixed systems of dipheonl, and so it had a potential application in the detection of dipheonl. Chapter four: PAN/PSF composite film electrodes were electropolymerized by cyclic voltammetry technique in sulfuric acid aqueous solution firstly, and then PtRu particles were deposited onto this composite film to obtain the PtRu-modified polyaniline/polysulfone (PtRu/PAN/PSF) electrodes.Their morphology and chemical component were characterized by SEM and EDS, respectively. The CV and EIS were applied to investigate the electrocatalytic activity of the PtRu/PAN/PSF electrodes and Pt/PAN/PSF electrodes. The results showed that PtRu particles were homogeneously dispersed in the porous polyaniline layer, and gained high dispersed composite film modification electrode. The electrochemical measurate showed that PtRu/PAN/PSF composite film electrode had a higher electrocatalytic activity and endure for the electrocatalytic oxidation of methanol than Pt/PAN/PSF electrode. Alloy formation