电化学沉淀法从废水中回收鸟粪石的试验研究-环境工程专业论文.docx

万方数据 万方数据 少了约 0.38~0.69mg/L，去除率则上升了约 18.4%，出水水质也较稳定；在增设电化 学沉淀装置后，出水的总氮浓度有了一定程度的下降，出水水质也能稳定达标，与单独 启动 A2/O 工艺相比，出水总氮浓度减少了约 0.17~0.31mg/L。 （6）对采取传统投加试剂法、以碳棒为阳极，不锈钢网为阴极的电化学沉淀法、 以及选用镁棒为阳极，不锈钢网为阴极的电化学沉淀法这三种方法处理 1t 污泥脱水滤液 进行运营成本估算。传统药剂投加法处理 1t 污泥脱水滤液费用为 14.19 元，碳棒为阳极 的电解沉淀法费用为 10.15 元，镁棒棒为阳极的电解沉淀法费用为 10.79 元。采用碳棒 做阳极的电解沉淀法处理 1t 脱水滤液比药剂投加法节省 4.04 元，采用镁棒做阳极的电 解沉淀法处理 1t 脱水滤液比药剂投加法节省 3.4 元。 （7）通过电化学沉淀法回收鸟粪石，不仅能够减轻污水处理厂的运营成本，降低 后续处理难度，且产生的高纯度鸟粪石可以用作农肥，此外利用镁做电解阳极，大大减 少了操作费用，产生的沉淀大部分富集在不锈钢网上，有利于工作人员收集鸟粪石沉淀； 将电化学沉淀法与其他工艺结合还能解决污水处理厂因面临污水处理排放标准升级而 需改造工艺费用较大的问题。 关键词：电化学沉淀；鸟粪石；影响因素；镁阳极；A2/O II Abstract Struvite(MgNH4PO4 · 6H2O) is a kind of white crystal poorly dissolved in water, it contains two kinds of nutrition elements nitrogen and phosphorus, which is a good slow-release fertilizer. Struvite can be formed in sewage 、 animal waste water and sludge dehydration liquor which is rich in nitrogen and phosphorus elements. Formation of struvite is an effective way to remove nitrogen and phosphorus pollutants from sewage and turn “waste” into “wealth” at the same time. Although nitrogen and phosphorous can be removed by means of struvite, which can be formed by adding chemicals or stripping carbon oxide in the wastewater, few studies focused on using electrochemical precipitation method to recover struvite. In order to explore the feasibility of recycling struvite by electrochemical precipitation, two series experiments, series Ⅰ and series Ⅱ, were carried out at first for determining the optimal operation conditions. In experiments, pH values were adjusted by the method of electrolysis. In series Ⅰ, the cathode was stainless steel, and the anode was carbon rod. In series Ⅱ, the cathode was stainless steel, and the anode was magnesium rod. Then, the treatment of domestic wastewater with the A2/O process and the combination of electrochemical precipitation and A2/O process were studied respectively. Conclusions are elicited as follows: When anodes were the carb