导电聚合物对电极在TiO2纳米管阵列基染料敏化太阳能电池中的应用-化学专业论文.docx

华侨大学硕士学位论文 华侨大学硕士学位论文 Abstract Abstract 万方数据 万方数据 万方数据 万方数据 与 EIS 数据表明，PAn 对电极还原 I3?的电化学催化活性与铂对电极相当，PAn 纳米带组装的 DSSC 光电转化效率为 6.32%，已达到铂对电极 DSSC 的 87%。 关键词：染料敏化 对电极 PEDOT PEDOT-PSS PAn II Abstract Generally, the dye-densitized solar cell (DSSC) consists of a dye-sensitized titanium dioxide (TiO2) nanoparticle photoanode, an I?/I3?electrolyte, and a counter electrode. The existed numerous boundaries among TiO2 nanoparticles result in slow diffusion rate of electrons and serious charge recombination between electrons and iodide ions in the electrolyte. Highly ordered, one-dimensional TiO2 nanotube arrays (TNTs) can provide direct electron transport channel, resulting in slower carrier recombination, longer electron lifetime, and higher electron transfer rate. Among the catalytic materials of counter electrodes, Pt is usually used. Whist it is a kind of nobel metal, which isn’t consistent with low-cost characteristic of DSSCs. Conductive polymers, such as poly(3,4-ethylenedioxythiophene) (PEDOT), poly(3,4-ethylene dioxythiophene): poly(styrenesulfonate) (PEDOT: PSS) and polyaniline (PAn), can be used as substitutes of Pt, owing to their low cost, easy fabrication, and high catalytic activity. In this paper, the main research contents and results are as follows: A 12.5 ?m double-ended open, one-dimensional ordered TNT film was prepared by a two-step anodization method and then detached from Ti foil with a 30 % H2O2 aqueous solution. Through HF and TiCl4 aqueous solution treatments, the roughness of TNTs film can be increased, resulting in the improved dye loading amounts and light harvesting efficiency. Combining HF with TiCl4 treatment, the highest power conversion efficiency (PCE) of DSSC can attain to 7.30%, with 35.69% enhancement compared with that of the non-treated one (5.38%). A high transparent PEDOT counter electrode is prepared with a simple method of in situ chemical polymerization of EDOT on fluorine doped tin oxide over-la