全钒液流电池离子交换膜性能研究-钢铁钒钛.PDFVIP

29 3 　　　 Vol.29, No.3 2008 8 　　　　 　　　　 IRON STEEL VANADIUM TITANIUM 　　　 　　　　　　 August 2008 冉洪波 (, 617000) 　:PE-01 Nafio 。:Nafio PE-01 , Nafio , , 、 , , 。PE-01 VO2+Nafio 。 :;;PE-01 ;Nafio + :TM911, TQ425.23 6　　:A　　:1004-7638(2008)03-0031-04 Study on Ion Exchange Membrane as a Separator for All-vanadium Redox Flow Battery Ra Ho gbo (Pa zhihua Iro a d Steel Research I stitute, Pa zhihua 617000, Sichua , Chi a) Abstract:The physical a d electrochemical properties of io excha ge membra e PE-01 a d Nafio were studied i all-va adium redox flow battery(VRB).It was show that the io excha ge capacity (IEC )a d chemical stability of Nafio membra e was better tha that of PE-01 membra e.I additio , Nafio mem- bra e with high co ductivity was suitable for high charge-discharge curre t, but it was easier for va adium solutio to permeate through the Nafio membra e tha the PE-01 membra e, leadi g to quickerwater tra s- port a d relatively lower coulombic efficie cy.The PE-01 membra e has fewer water tra sport volume a d 2+ lower VO diffusibility tha Nafio membra e. Key words:Io excha ge membra e;all-va adium redox flow battery;PE-01 membra e;Nafio membra e 储液罐中的溶液可能溢出。所以通过改性处理, 寻 0 　引言 求一种价格便宜、较高电导率, 选择渗透性好、水迁 　　全钒氧化还原液流电池 (VRB)成功商业化吸 移量小, 可以完全满足VRB 长期应用的理想隔膜至 引了众多科技人员对廉价微孔膜及少 阴、阳离子 关重要。笔者以全钒液流电池为例, 以PE-01 膜和 [1～5] Nafio 117 膜为离子交换膜,在实验室就这两类膜在 交换膜的性能进行了研究 。与电池常用的多孔 隔膜不同, 离子交换膜在液流储能电池中起着双重 全钒液流电池中的应用特性进行了研究。 作用, 既要分隔正、负极电解液,又要传导离子,形成 1　实验 电流回路,是决定液流电池性能的关键材料,