Al-Zn-In-Mg阳极低温海水环境电化学性能研究-腐蚀科学与防护技术.PDFVIP

第30 卷 第4 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol. 30 No. 4 2018 年7 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Jul. 2018 Al-Zn-In-Mg 阳极低温海水环境电化学性能研究 王海涛 许 实 王 辉 王洪仁 青岛双瑞海洋环境工程股份有限公司 青岛 266101 摘要 通过恒电流极化、动电位扫描、电化学阻抗、金相组织观察、扫描电镜和能谱分析等方法和腐蚀失重实 验，研究了Al-Zn-In-Mg 牺牲阳极在低温和常温环境的电化学性能和腐蚀过程，结果表明：Al-Zn-In-Mg 阳极在 低温和常温环境下都具有良好活化性能，在3 和20 ℃天然海水中电容量分别达到2678 和2571 A h kg-1 ，阳极 ·· 表面溶解均匀，低温环境阳极开路电位和工作电位负移，其电化学性能达到阴极保护材料性能要求。通过极 化曲线、电化学阻抗和腐蚀失重实验证明Al-Zn-In-Mg 阳极在低温环境下阳极自腐蚀速率降低，自身消耗降 低，从而导致了阳极低温海水中电化学性能优于常温环境。 关键词 铝牺牲阳极 低温 电化学性能 扫描电镜 中图分类号 TG 174.3 文章编号 1002-6495(2018)04-0413-06 Electrochemical Performance of Al-Zn-In-Mg Sacrificial Anode in Cold Seawater WANG Haitao, XU Shi, WANG Hui, WANG Hongren Sunrui Marine Environment Engineering Co., Ltd., Qingdao 266101, China Correspondent: WANG Haitao, E-mail: wanght@sunrui.net Manuscript received 2017-10-25, in revised form 2017-11-24 ABSTRACT The corrosion behavior and working performance of Al-Zn-In-Mg sacrificial anode were studied in natural seawater at 3 and 20 ℃ respectively by means of gravimetric test, measurements of constant current polarization and potentiodynamic polarization, as well as electrochemical impedance spectroscopy, metallographic microscope, SEM with EDX. Results indicated that Al-Zn-In-Mg anode had good activation behavior in cold and normal temperature seawater. The Al-Zn-In-Mg anode presented uni- form surface dissolution with electric capacities of 2678 and 2571 A h kg-1