从玻璃纤维池窑废耐火浇注料中回收提取铂和铑-有色金属材料与工程.PDF

32 1 V o.l 32, No. 1 2 0 1 1 3 SHANGHA INONFERROU SMETALS M arch, 2011 : 1005- 204 ( 2011) 01- 0004- 04 1 2 1 1 1 1 毕鹏飞 , 王松泰, 谈定生 , 刘国永 , 樊 荣, 吴远桂 ( 1. , 200072; 2. , 201900) : 以玻璃纤维行业生产的废耐火材料为原料, 采用王水溶解离子交换溶剂萃取和萃 树脂分离为主要方法回收纯铂铑, 得到了良好的提取效果结果表明, 采用该工艺, 铂铑的回收 率可达 90% 以上, 制得的海绵铂和铑粉的纯度均大于 99. 95% : 废耐火浇注料; 玻璃纤维; 铂; 铑; 回收 : TF803. 2 : A Recovery of Platinum and Rhodium from Spent Castable Refractory in Glass Fiber Furnaces 1 2 1 BI Peng-fei, WANG Song-tai, TAN D ing-sheng, 1 1 1 LIU Guo-yong, FAN Rong, WU Yuan-gui (1. D ep artm ent of M aterial Engineering, Shanghai University, Shangha i200072, China; 2. N o. 2 Steelma ing P lant, Baoshan Iron S teelCo. L td. , Shanghai 201900, China) Abstract: The recovery and purification of platinum and rhodium from spent castable refractory of glass fiber industry are d iscussed. The platinum and rhodium w erew ell extracted by a series of treat- ments includ ing aqua regia dissolution, ion exchange, solvent extraction and levextrel resin separa- tion. The results show that the recovery rates of platinum and rhodium can be over90%, and the pu- rities of the prepared sponge platinum and rhod ium powder can be greater than 99. 95% . K ey words: spent castable refractory; glass fiber; platinum; rhod ium; recovery , 0 , , ,