A01.能量转换和存储材料.PDFVIP

A01.能量转换与存储材料 分会主席：武英、潘洪革、黄学杰、李箭 A01-01 LiNi0.5Mn1.5O4 as cathode material for Li-ion Batteries 黄学杰 中国科学院物理所 Electrical vehicles represent one approach to reduce undesirable emissions from conventional internal combustion engines in heavily populated areas. Li-ion battery is becoming the key enabling technology for EVs. Presently, Li-ion batteries with LiMn2O4, NCM/NCA, LiFePO4 as cathode active material are widely used in EVs. High-voltage spinel LiNi0.5Mn1.5O4 cathode material has specific energy (~640 mAh/g due to the high operation voltage of ~4.7 V. The relatively inexpensive Ni and Mn in LiNi0.5Mn1.5O4 make this cathode material particularly desirable for large-scale applications. A detailed investigations of its local atomic-level structure with lithium extraction/insertion is observed via an aberration-corrected scanning transmission electron microscopy (STEM). The surface regions (~ 2nm) show an irreversible migration of TM ions into lithium tetrahedral sites to form a Mn3O4-like structure. It contributes to the dissolution of TM ions as well as the rocksalt-like structures with heavy TM ions on the lithium pathways blocks the migration of lithium ions, resulting in building-up of charge transfer impedance and degradation of capacity. When the surface LiNi0.5Mn1.5O4 was modified by Ti4+ and Ta5+ superficial doping, the cycling performance of the material at elevated temperatures has been much improved and the coulombic efficiency of discharge/charge is also obviously increased. Theoretical calculations analyses reveal that the stability of O at surface layer is enhanced by those surface modifications and detailed analyses will be reported. A01-02 层状富锂锰基征集材料的研究进展 夏定国 北京大学 A01-03 Development of separators for hi