la0.5sr0.5coo3-δ导电陶瓷纤维的静电纺丝法制 备跟表征新.pdfVIP

Material Sciences 材料科学, 2018, 8(3), 153-161 Published Online March 2018 in Hans. /journal/ms /10.12677/ms.2018.83019 Fabrication and Characterization of La0.5Sr0.5CoO3-δ Fibers by Electrospinning * Qiyi Cao , Qing He, Zhaofei Tong, Siyi Chen, Xiangang Long School of Mechanical Engineering, Quzhou University, Quzhou Zhejiang th st th Received: Feb. 28 , 2018; accepted: Mar. 21 , 2018; published: Mar. 28 , 2018 Abstract Using metal nitrates, citric acid, ethylene glycol and polyethylene pyrrole (PVP) as precursors, La0.5Sr0.5CoO3-δ (XRD) fibers were fabricated via sol-gel method, electrospinning and subsequent heating process. The thermal decomposition process, crystal structure, morphology and element distribution of the as-pun and as-calcined fibers were studied by means of thermogravime- tric-dlifferential thermal analysis (TG-DTA), X-ray diffraction (XRD), scanning electron microsco- py (SEM) and energy dispersive spectrometer (EDS), respectively. The results show that: the op- timum preparation conditions are that the spinning forming agent is prepared by 3.5 wt% PVP with the average molecular weight of 1,300,000, and the concentration of metal ions is 0.125 mol/L. The spinning speed can reach up to 9 ml/h under these conditions. After annealing the LSCO precursor fiber at 800˚C, LSCO ceramic fibers with diameters ranged from 0.5 μmto 2 μm were successfully obtained. Keywords La0.5Sr0.5CoO3-δ Fibers, Conductive Ceramic, Electrospinning, Electrical Contact Material La0.5Sr0.5CoO3-δ导电陶瓷纤维的静电纺丝法制 备及表征 * 曹奇益，贺 庆，童兆飞