FClH2HD=1反应的态态动力学研究.docx

优秀毕业论文 精品参考文献资料 F／ F／CI+H2／HIXv=1)反应的态一态动力学研究 ABSTRACT One ofthe most intriguing aspects ofreaction dynamics is to study mechanism ofchemical reactions with reagent in certain quantum state．Development of laser technique brings a new era to US，which Can not only help to detect the product but also control the reagent in a specific quantum state． Hydrogen is the most abundant element in the universe．Although chemical reactions involving hydrogen had attracted much attention，most of these studies were focused on the ground state due to technical difficulty of H2 molecules vibrational excitation．It is challenging to carry out the experimental study of reaction dynamics involving vibrationally excited H2 molecules． In this thesis，I participated in developing a single—longitudinal mode and high power nanosecond laser system．Combined this laser system with the high resolution time—of-flight Rydberg tagging apparatus．more than 1 3％population transfer from v=O to 1 of HE was demonstrated with the scheme of stimulated Raman Pumping in the crossed molecular beam experiment．These results provided an opportunity to study reaction dynamics involving vibrationally excited hydrogen molecules． Reaction resonances were firstly found in the state-to-state dynamics study ofCl+HD(v：1， 产0)_DCI+H reaction．The reaction of C1+HD has always appeared to proceed via a direct abstraction mechanism，诹th no clear signature of reaction resonances．In this study，oscillatory structures were detected at the backward direction from the collision energies of 1．9 to 4．9 kcal／m01．The structures attributed to reaction resonances related to the states trapped in the peculiar H—DCI(v=2)vibrationally adiabatic potential well by the calculations．We anticipate that similar resonance phenomena may occur in a broad range of chemical reactions involving vibrationally excited molecules． At the collision energy of 0．52 kcal／mol，the forward scattering peak of the HF(v’=2) product，which was attributed to Feshbach re