《烷基咪唑四氟硼酸离子液体的合成及其水（乙醇）溶液体系电导的测定》-毕业设计论文（公开).docVIP

PAGE PAGE I l XXX大学 毕 业 论 文 ***届 烷基咪唑四氟硼酸离子液体的合成及其水（乙醇）溶液体系电导的测定 学生姓名 XXX 学 号 XXX 院 系 XXXX 专 业 XX 指导教师 XX 完成日期 XXX 烷基咪唑四氟硼酸离子液体的合成及其水（乙醇）溶液体系电导的测定 摘 要 以N-甲基咪唑、卤代烷烃及四氟硼酸钠为原料合成烷基咪唑四氟硼酸离子液体1-丁基-3-甲基咪唑氟硼酸盐 ([Bmim]BF4)和 1-辛基-3-甲基咪唑氟硼酸盐([Omim]BF4)。用电子天平以称重法配制一系列烷基咪唑四氟硼酸离子液体与水（乙醇）组成不同摩尔分数的二元体系，即：[Bmim]BF4 + 水 (乙醇) 体系、[Omim]BF4 + 乙醇体系、1-乙基-3-甲基咪唑氟硼酸盐 ([Emim]BF4) + 水体系、1-丁基-2，3-二甲基咪唑氟硼酸盐 ([Bmmim]BF4) + 水 (乙醇) 体系。用DDS-307电导率仪测定了上述6个体系在298.15K时的电导率。结果表明，电导率均随离子液体浓度的增加先增加后降小；在水溶液中电导率的大小顺序为：[Emim]BF4 [Bmim]BF4 [Bmmim]BF4，在乙醇溶液中电导率的大小顺序为: [Bmim]BF4 [Bmmim]BF4 [Omim]BF4。表明阴离子相同的该离子液体，其电导率主要取决于咪唑阳离子的体积大小：即取代基越大电导率越小；在相同浓度时离子液体在水中的电导率大于在乙醇中的电导率。 关键词 烷基咪唑氟硼酸盐；离子液体；二元体系；电导率 THE SYNTHESIS OF ALKYL IMIDAZOLIUM TETRAFLUOROBORATE IONIC LIQUIDS AND MEASUREMENT OF THEIR CONDUCTIVITY WITH WATER OR ETHANOL ABSTRACT Alkyl imidazolium tetrafluoroborate ionic liquids 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4) and1-methyl-3-methyl imidazolium tetrafluoroborate ([Omim]BF4) was synthesized through the N-methylimidazolium, halogenated alkane, and sodium fluoride. The binary mixtures of [Emim]BF4 + water, [Bmim]BF4 + water or ethanol, [Bmmim]BF4 + water or ethanol, and [Omim]BF4 + ethanol were prepared using an analytical balance. Conductivities of the above-mentioned systems were measured at 298.15 K used a DDS-307A digital conductivity meter. The results indicated that the conductivity of the above-mentioned systems increased initially and then decreased as the concentration of the ionic liquids increased. The conductivity of ionic liquids with water follows the order: [Emim]BF4 [Bmim]BF4 [Bmmim]BF4, and that of ionic liquids with ethanol follows the order: [Bmim]BF4 [Bmmim]BF4 [Omim]BF4, indicating the larger size of the cation, the lower conductivity in solvent. The conductivity of ionic liquids with water was larger than that of ionic liquids with ethanol at the same concentration. KEYWORDS Al