HACFPEEK多层复合材料制备与力学性研究.docxVIP

摘要摘 摘要 摘 要 通过原位合成．多层复合．热压成型相结合技术制备re(HA．CF)／PEEK多层复合材 料。采用XRD、FT．IR和SEM等检测设备对多层复合材料的显微形貌、显微结构和 组织成分进行观察和分析；通过表面沉积HA实验评价了制备工艺条件对 (HA—CF)／PEEK多层复合材料生物活性的影响变化规律；系统研究了制各工艺条件对 (HA—CF)／PEEK多层复合材料拉伸和弯曲力学性能的影响规律及断裂机理和增强机 理。得到如下主要结论： 1．XRD分析结果表明热压成型制各过程中不会改变PEEK、CF及HA的组织成 分及结构；FT-IR分析结果表明CF经过浓硝酸处理后，其表面上引入了含氧的活性 基团；SEM分析结果表日．fl(HA．CF)／PEEK多层复合材料是拥有3层且每个界面都能平 滑过渡的类似夹心板结构的复合材料；通过生物矿化实验(表面沉积HA)表明 (HA．CF)／PEEK多层复合材料具有良好的生物活性。 2．HA／PEEK复合材料的拉伸强度及断裂应变随着HA含量的增加而下降，且退 火处理明显提高了拉伸强度。 3．碳纤维的表面处理对CF／PEEK复合材料力学性能影响显著。浓硝酸处理后的 cF／PEEK复合材料的力学强度最好，且拉伸强度随着CF含量的增加先上升后下降， 最大值出现在CF为25嘶％处；弯曲强度随着CF含量的增多而增大；KH．560处理 CF对CF／PEEK复合材料力学性能影响甚微。 4．(HA—CF)／PEEK多层复合材料拉伸和弯曲强度均随HA含量的增加而下降， 但其拉伸强度优于HA／PEEK复合材料的拉伸强度，这主要是由于中间层 20％CF／PEEK复合材料的增强作用。 5．(HA。CF)／PEEK多层复合材料拉伸强度随着CF含量的增加，先下降后上升， 且拉伸强度最低时的CF含量为15谢％；弯强度随着CF含量的增加而增加。 关键词：羟基磷灰石；聚醚醚酮；碳纤维；多层复合材料；力学性能 分类号： 万方数据 万方数据 万方数据 安徽理工大学硕士学位论文Abstract 安徽理工大学硕士学位论文 Abstract In this paper，O执一CF)／PEEK multilayer composites were prepared by in situ synthesis—layered laid—hot pressing molding．The microscopic morphology，microstructure and tissue composition(HA—CF)／PEEK multilayer composites were analyzed by XRD， FT-IR and SEM．The influence of the preparation process conditions on bioactive of 衄～一CF)／PEEK multilayer composites was evaluated by the surface sedimentary HA experiment．The influence of the preparation process conditions on the tensile and flexural mechanical properties， fracture mechanism and strengthening mechanism of (HA—CF)／PEEK multilayer composites WaS studied． 1．XRD analysis indicated tllat the tissue composition and structure PEEK，CF and HA were not changed．FT-IR analysis indicated that CF surface was introduced in oxygen—containing groups when CF was modified晰th concentrated nitric acid．SEM analysis indicated that(HA—CF)／PEEK multilayer composites was to have 3 layers and each interface could smooth transition similar sandwich board structure of composites，and (HA—CF)／PEEK multilayer composites had good biological activity． 2．The tensile mechanical strengt