苏州科技学院天平学院本科生毕业设计（论文） 城市饮用水管网末梢低余氯光滴定分析研究.docVIP

苏州科技学院天平学院本科生毕业设计（论文） PAGE \* MERGEFORMAT II 城市饮用水管网末梢低余氯光度滴定分析研究 摘 要 自来水中超低余氯的测定是分析难点，常规滴定法难以保证低浓度结果精确度；常规分光光度法中以碘酸钾标准溶液取代余氯标准带来测定误差。本实验采用研制的激光超长光程光度滴定仪器，进行低浓度余氯微量滴定分析研究。经过实验及反复有效测定，并与常规的DPD目视滴定法测定自来水中的余氯进行比较，采用超长光程的微量光度滴定分析方法测定低余氯精确度较高，检出限最低可以达到0.01 mg/L，达到了我国《生活饮用水卫生标准》所规定的城市饮用水管网末梢水质0.05 mg/L的余氯低检测范围。我们试验研究的DPD光度滴定法测定自来水超低余氯浓度，取得满意的效果。这也为管网水质自动监测开拓了较理想的技术路线。 关键词 水中余氯；微量滴定；光度滴定 Photometric titration analysis research of Low residual chlorine in urban water pipe endings Abstract The analysis of low residual chlorine in tap water is a hard work, because conventional titration method to ensure the accuracy of low concentration is not easy.Conventional spectrophotometry in iodide-iodate potassium standard solution instead of residual chlorine standards brings measuring error. This experiment with the laser optical path and photometric titration instrument, low concentration residual chlorine trace titration analysis. Through experiments and repeatedly effective measurement, and with the conventional DPD visual titration compared the residual chlorine water, using the ultra-long light trace photometric analysis method for determining titration accuracy is higher, low residual chlorine detection limit minimum can achieve 0.01 mg/L, reached the 0.05 mg/L tips of residual chlorine low detection range in《Drinking water hygiene standards》. We test the research DPD photometric titration low residual chlorine water concentration, with satisfactory results. This is for water quality automatic monitoring the ideal technology route. Keywords Water residual chlorine； Micro titration；Photometric titration PAGE \* MERGEFORMAT 58 目 录 TOC \o 1-3 \t 参考文献,6,附录,7,结论,4,致谢,51 绪论 PAGEREF _Toc1928 1 2 水中余氯化学氧化还原滴定的测定（DPD滴定法） PAGEREF _Toc12509 4 2.1 氧化还原滴定余氯实验准备 PAGEREF _Toc16849 4 2.1.1 实验试剂 PAGEREF _Toc9031 4 2.1.2 仪器设备 PAGEREF _Toc20580 5 2.2 常规标准余氯滴定分析法（DPD）试验研究数据分析 PAGEREF _Toc26949 5 2.2.1 硫酸亚铁铵贮备液浓度标定 PAGEREF _Toc16362 5 2.2.2 硫酸亚铁铵标准滴定液的浓度 PAGEREF _Toc4688 6 2.2.3 不同