化学包裹粉工艺制备粗晶粒WC-Co硬质合金-中国有色金属学报.PDFVIP

20 4 2010 4 Vol.20 No.4 The Chinese Journal of Nonferrous Metals Apr. 2010 1004-0609(2010)04-0701-05 WC-Co ( 410083) 8.06 µm WC Co(NO ) ·6H O N(CH CH OH) (TEA) 3 2 2 2 2 3 WC-12%Co() WC-12%Co WC X TEA Co Co fcc WC WC-12%Co 4.8 µmWC WC Co Co TF125.3 A WC-Co cemented carbide from porous spumous cobalt enwrapped WC powders by chemical route WU Hou-ping, ZHANG Li, WANG Yuan-jie, HUANG Bai-yun, CHENG Xin (State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract: The WC-12%Co (mass fraction) cemented carbide with an average grain size of 4.8 µm and homogeneous microstructure was prepared from porous spumous cobalt enwrapped tungsten carbide powders produced by a novel chemical route. The tungsten carbide powder with Fisher sub-sieve sizer granularity of 8.06 µm and cobaltous nitrate hexahydrate were used as the starting materials, and the triethanolamine (TEA) was used as the reducer. The phase constitutes and morphology of the powders were investigated by X-ray diffractometry and scanning electron microscopy, respectively. BET specific surface area analyzer was used to analyze the porous spumous cobalt reduced with TEA. The microstructure of WC-Co cemented carbide was observed by metallographic microscopy. The results show that, in the cobalt enwrapped WC powders, cobalt exists in pure face centered cubic structure in the form of nano particles assembly. The tungsten carbide gra