加州大学伯克利分校有机化学第十章.pptVIP

? University of California ? Univesity of California Chapter 10: Nuclear Magnetic Resonance (NMR) Spectroscopy A General Spectrometer Protons as Tiny Magnets Line Up With and Against an External Magnetic Filed Absorption of Light, Spin Flip, and Resonance ? Spectral Line A Hypothetical NMR Spectrum: Active Elements Absorb at Differing Frequencies The NMR Spectrometer High Resolution NMR! The Chemical Shift δ Application of δ Integration Spin-Spin Splitting (N+1) Rule Summary Points Complex Splitting Patterns Ribonuclease A, 40 MHz “Sequential” [N+1] Rule Stereocenters and Methylene Groups H