聚碳硅烷二乙烯基苯快速升温裂解制备CfSiC复合材料.PDFVIP

25 2 JOUR AL OF ATIO AL U IVERSITY OFDEFE SE TECH OLOGY Vol.25 o.2 2003 :1001- 2486(2003) 02- 0030- 04 X /C/SiCf ,, , ( , 410073) :(PCS)/(DVB), 3D- B C/ SiC f :,, C/ SiC 55617MPaf :; ;; ; :TQ343 :A Fabrication of C/ SiC Composites by Pyrolysis Precursorf PCS/ DVB at High Heating Rates JIA Ke,CHE Zhao2hui, MA Qing2song,Zheng Wen2wei (College of Aerospace and Materials Engineering, ationalUniv. of Defense Technology, Changsha 410073, China) Abstract:Three2 dimensionalbraided carbon fiber (3D- B CF) reinforced SiC composites were fabricated via infiltration and pyrolysis of polycarbosilane(PCS)/divinylbenzene (DVB). The results show that increasing pyrolysis heating rates can reduce cycle time ofmanufacturing. At the same time, it can increase the density of C/ SiC materials and improve the interface be2 f tween carbon fiber and SiC matrix. The flexural strength ofC/ SiC materials reachs 556.7MPa.f Key ords:ceramicmatrix composites; pyrolysis heating rates; polycarbosilane; flexural strength; interface C/ SiC, f C/ SiC , (PIP)f , PCSSiC, , ,015 e /min , DVB, [1] , , 2e /min , 3D2B C/ Sif 3 4 [2] , , PCS/DVB,3D2B C/ SiCf 1 1. 1 3 : 3K , 1176g/ cm , 3000~ 3300 MPa,210GPa3D2B, 8B1B1, 50% , , 217~ 227e X :2002- 11- 28 :863 :( 1979) ), , , :/ C/ SiC f