碱性燃料电池氧但电极及co-nc催化材料研究.docxVIP

硕十学位论文 硕十学位论文 摘要 摘要 本论文的工作主要研究了几种不同碳素材料对氧还原反应的活性 及碳素材料的处理对其活性的影响；研究了Co．N／C复合材料的制备及 其在碱性介质中对氧还原反应(ORR)、氧析出反应(OER)的电催化性能； 同时研究了气体扩散电极的制备工艺，如电极厚度、PTFE含量及热处 理温度等重要参数，以制备对氧还原、氧析出具有最佳性能的电极。 室温时，未经处理的碳电极无论是对氧还原，还是氧析出都只有有 限的催化能力；碳粉经酸处理可以显著提高碳电极的催化性能，在空气 中．0．2 V(VS．HgO／Hg)和0．6 V(VS．HgO／Hg)电位下，ORR和OER的电流 密度分别达到57 mA·cm{和30 mA·cm～，说明在氧扩散电极中，碳材 料不仅是催化剂载体，也是电极反应的的活性部位。它的孑L结构和表面 性质直接影响催化剂对氧还原的活性和选择性。 在碳粉中加入醋酸钴经氨气高温处理制备了Co．N／C复合材料。 XRD物相分析表明生成了氮化钻(C05．47N)；电极在．0．2 V(vs．HgO／Hg) 时ORR电流密度可达170 mA·cm～，0．6 V(VS．HgO／Hg)时OER电流密 度可达80 mA·cm-2，显示出Co．N／C催化材料在碱性电解液中对氧还原、 氧析出优异的电催化性能。交流阻抗显示氮化物的生成减小了氧还原反 应的电荷传递阻抗，大大增强了对氧还原反应的电催化作用。 关键词．J 碳电极，氧还原，氧析出，氮化钴，电流密度 硕十学位论文 硕十学位论文 ABSTRACT ABSTRACT This work mainly studied Co—N／C complex catalytic material for Oxygen Reduction Reaction(ORR)and Oxygen Evolution Reaction(OER) in fuel cells，including its electro-catalytic performance，equivalent circuit and kinetic parameter．Various carbon materials for carrier of gas diffusion electrode(GDE)，the thickness of the electrode and different treatments ．were also studied in this work to prepare GDE．which call make ORR or OER present the best electrochemical performance． At room temperature，the carbon powder without anytreament contributed limited electrocatalytic ability for ORR and OER．Ⅵ恤en the carbon powder was treated by hydrochloric acid and nitric acid，the current density of the carbon electrode in the air condition increased to 57 mA·cmz at potential of-0．2 V versus an Hg／HgO reference electrode，and current density was 30 mA·cm～for OER．It showed that carbon black not only acted as cartier,but also its hole fabric and apparent status Can affect the activity and selectivity for ORR and OER． Co-N／C complex material was prepared by adding cobalt acetate followed by heat．treatment with am