农业秸秆活性炭时改性及处理含汞废水的研究-环境科学专业毕业论文.docxVIP

Hg(II)的去除率达到99．8％，未改性活性炭仅为80％左右；吸附平衡时，改性活 Hg(II)的去除率达到99．8％，未改性活性炭仅为80％左右；吸附平衡时，改性活 性炭的吸附量为33．10mg／g，远大于未改性活性炭的11．67mg／g。活性炭的吸附过 程为吸热反应，但不同温度条件下，活性炭的吸附性能差异并不明显。活性炭对 Hg(II)的吸附符合Freundlich方程，吸附机制为多分子层吸附，吸附动力学符合 Lagergren准二级动力学模型，吸附类型主要以化学吸附为主。 3．改性活性炭对模拟含汞废水的处理效果受pH、接触时间的影响明显。在 活性炭用量为49／L，模拟废水Hg(II)浓度为30mg／L的条件下，最佳处理pH为5， 接触时间为5h，Hg(II)l掏去除率为72％，工艺试验结果与实验结果有相当的差 距。 主要结论：秸秆活性炭经掺硫改性后，显著地改善了活性炭的表面吸附性能。 改性活性炭对Hg(II)吸附受pH、吸附剂用量和初始浓度的影响明显，但受温度 的影响不大；活性炭对Hg(II)的吸附过程符合Freundlich方程，吸附动力学符合 Lagergren准二级动力学模型，吸附机理为多分子层吸附，吸附类型主要以化学 吸附为主，吸附热力学为吸热反应。 关键词：含汞废水秸秆活性炭改性吸附 Ⅱ 万方数据 Research Research on Modified of Straw．．based Active Carbon and Its Applied to the Processing Mercurry—·bearing 肋sterwater Major：Envionmental Science Candidate：Chen Zhuoer Supervisor：He Lei Abstract：Mercury wastewater is a kind of wastes with heavy metal discharged in the process of industrial products．It is known the harm of mercury wastewater and a variety of physical,chemical and biological treatments have been developed． However,there are still many disadvantages in these treatments tO limit the engineering application．It is considered as of the important sources of mercury pollution in environment．Along with the higher mercury emission thresho ld in both international and domestic policies，it is crucial that high-efficiency,low·comumption and low-cost treatments materials and technologies to be developed，to ensure the emission standard．Therefore，agricuRural crops straw activated carbon was used as material in this research．After the modification,the characteristics and mechanisms of adsorption and the influence factors of modificated activated carbon had been studied，to find out the parameters in treatment of mercury wastewater．The aim is to provide scientific basis to develop low·cost，high—efficient and environmental friendly mercury adsorption materials．Results showed that： 1．Activated carbon adsorption performance was influenced by modified conditions． There were remarkable differences in the Hg(II)ad