前体法制备复合金属氧化物氮化碳复合材料及其光驱动过氧化氢形成机制关研究-化学专业毕业论文.docxVIP

北京化工大学硕士学位论文能够顺利地进行水氧化反应产生质子氢(H十)，从而使得质子氢(H+) 北京化工大学硕士学位论文 能够顺利地进行水氧化反应产生质子氢(H十)，从而使得质子氢(H+) 与分子氧(02)相结合还原生成过氧化氢(H202)产物。该研究为 高效低成本产过氧化氢的复合结构光催化剂的设计提供了重要思 路。 关键词：光催化，双金属(氢)氧化物，过氧化氢 万方数据 ABSTRACTPREPARATIoN ABSTRACT PREPARATIoN oF COMPoSITE METAL oXIDE／CARBoN NITRIDE CoMPoSITES BY PRECURSoR METHoD AND STUDY oN THE FoRM√气TIoN MECHANISM oF LIGHT DRIVEN HYDRoGEN PERoXIDE ABSTRACT Demand for energy is more and more urgent in today’S society, however,Energy shortages and environmental degradation are increasingly prominent．Converting solar energy into heat energy, electrical energy,chemical energy is an important way to solve the energy problem．As a kind of solar fuel，hydrogen peroxide Can make it pollution-flee throughout the process of source of energy,conversion and final product．Hydrogen peroxide is also a versatile clean oxidant that is widely used for pulp bleaching，wastewater treatment， disinfection，and organic synthesis．At present，the design of effective photocatalyst for production of hydrogen peroxide clean and safe is still full of challenging． 万方数据 北京化工大学硕士学位论文This 北京化工大学硕士学位论文 This work developed a non-noble metal photocatalyst with the i nteraction of double metal oxide or metal hydroxide with other materials．The core content in this article is： Composite precursor was obtained by simple hydrothermal reaction， and the composite Was successfully obtained by the calcination of the precursors．The mixed metal oxide or carbon nitride alone cannot produce hydrogen peroxide in water system，however the mixed metal oxide／carbon nitride composite material photocatalyst faci litates highly efficient production of H202．The yield of H202 at 3h can reach 67 l上mol／L．It is ascribed to the positive shift of the position of conduction band and valence band after the combination of MMO and carbon nitride．The position shift of conduction band can still carry out oxygen reduction reaction，and the position shift of valence band makes it more easy to carry out water oxidati