双功能性纳米结构的构建-无机化学专业毕三业论文.docxVIP

中文摘要双功能性纳米结构的构建 中文摘要 双功能性纳米结构的构建 中文摘要 采用溶剂热处理法，制备了复合CdTe量子点的Fe304纳米线，并使用XRD、TEM、 FESEM、PL、VSM等测试手段对其微观形貌，结构及成分进行了表征，此复合物具 有优良的磁，光特性。 通过纳米颗粒的自组装制各了多孔性的ZnO／ZnS微球并以装载CdTe量子点为例 研究了它们在主客体化学中的应用。采用XRD、TEM、FESEM、PL等测试手段对所 得产物进行了表征，发现CdTe量子点的引入导致了光致发光微米球的形成。可以预 料到，除了量子点之外，其它的功能单位如磁性和有催化活性的纳米颗粒也能被引入 核壳结构的系统中。 以多孔性的ZnO／ZnS微米球为前驱体制备出了7-Fe203修饰的双功能性ZnO／ZnS 带状物，采用XRD、TEM、HRTEM、PL、VSM等测试手段对产物的形貌、结构、组 成、及光学、磁性性质等进行了表征。此复合物结合了ZnO和ZnS的光致发光效应 和丫．Fe203的铁磁性。探讨了实验过程中所加沉淀剂的种类、碱液的浓度、反应所需 的时间及温度等条件对生成产物的影响。 单一组分的纳米晶由于受有限组分的制约，它们的性质和功能单一。通过构建各 种双功能性的纳米结构，成功地克服了这些缺点。所制备的CdTe／Fe304、ZnO／ZnS、 T-Fe20JZnO／ZnS纳米复合材料具有单独组分不具有的独特性能。这些纳米复合材料 作为新型的结构、功能材料将在光、电、磁等领域展现出广泛的应用。 关键词：纳米复合材料：溶剂热法；自组装；双功能性 作 者：兰仙梅 指导老师：曹雪波副教授 Construction Construction of bifunctional nanostructures Abstract Construction of Bifunctional Nanostructures Abstract Long Fe304 nanowires decorated by CdTe quantum dots were synthesized through solvothermat treatment．nle morphology，structure，and composition of the composite nanowires were characterized by means of the XRD，TEM，FESEM，PL，and VSM．T11e as-prepared nanostructure retains not only the good ferromagnetism of Fe304 but also the strong photoluminescence effect of CdTe QDs． Wim a self-organization method，we successfully prepared porous ZnS／ZnO composite microspheres in a large scale and studied their application as supports of CdTe quantum dots．The microspheres were characterized by means ofXRD，TEM，FESEM，and PL．CdTc quantum dots were introduced into the nanopores to achieve luminescent microspheres．And it is expected that,besides semicondueting quantum dots，other functional units，such as magnetic and catalytically activated nanoparticles，Can also be introduced into them． Polycrystalline ZnO／ZnS nanoribbons decorated by y-Fe203 clusters were synthesized by a two-step，solution-based method．nle growth of the nanofibbons is clarified to be dominated by a dissolution—reconstruction mechanism．The morphology， structure， composition,optical and magnetic properties of the nanoribbons