《焦化蜡油络合脱碱氮技术研究》-毕业设计（论文）.docVIP

大庆石油学院工程硕士专业学位论文论文题目：焦化蜡油络合脱碱氮技术研究 大庆石油学院工程硕士专业学位论文3焦化蜡油络合脱碱氮技术研究摘要本文综述了国内外焦化蜡油脱除碱性氮化物的工艺方法及工艺条件，并讨论了具有质子特征的脱氮剂与焦化蜡油中的碱性氮化物络合反应机理。试验主要针对大庆石化公司炼油厂生产的焦化蜡油和重催原料油，通过采用络合脱氮剂脱除碱性氮化物。首先通过焦化蜡油和重催原料油的静态脱碱氮试验，筛选了适用于焦化蜡油脱除碱性氮化物的络合脱氮剂，优选的脱氮剂为ＴＤ－２型脱氮剂，并且确定了脱氮剂加入量，当脱氮剂加入量为0.4％时，脱氮率达到49.53％；通过对脱氮精制前后的焦化蜡油按不同的掺混比例模拟实际工业操作条件，进行提升管催化裂化对比试验，试验结果表明，焦化蜡油脱氮精制前后的催化裂化产品收率表现出明显差异性，脱氮精制后焦化蜡油催化裂化轻油收率随脱氮剂用量的增加有一个极大值，在极大值处（0.25-0.35%）轻油收率增加3-4%。从而确定了络合法脱除焦化蜡油中的碱性氮化物的工艺路线。其次通过络合氮化物分解实验，考察了络合氮化物分解情况与温度的关系，试验结果表明碱氮含量随着温度的升高而缓慢增大，但变化较小，络合氮化物不存在分解；通过脱氮剂罐的腐蚀试验，表明脱氮剂对脱氮剂罐及管线的材料不存在腐蚀作用；通过动态挂壁试验，脱氮剂蒸发量试验确定了脱氮剂在脱氮剂罐内的使用温度为≯75℃等脱氮最佳工艺条件，完成了工业化的准备实验。关键词：焦化蜡油；络合脱氮剂；碱氮 前言4Study on Technology to Separate BasicNitride from the Coking Wax OilABSTRACTThis paper introduced the technological method and technological conditions and discussedthe reaction principle for separating basic nitride from coking wax oil.According to thefeature of the Daqing coking wax oil,an efficient and economical liquid phase complexationdenitrification additires has been studied and produced.We determined composition andquantitation of the complexation denitrification additires by static experiment.The bestcomplexation denitrification additires is TD-2.Using this technology,when adding 0.4%complexation denitrification additires the rate of removing basic nitride is up to 49.53%.Theexperimental simulation of reaction in commercial FCC riser processing mix oil was conductedin a riser pilot plant.The experiment shows with the increase of complexation denitrificationadditires,the yield of the light oil has a maximum and it can increase 3-4%.The materialof complexation denitrification additires pod and tempreture of complexation denitrificationadditires are determined by corroding experiment of complexation denitrification additirespod,kinetic experiment and complexation denitrification additires evaporating experiment.Wedetermined the best technological conditions and completed the preparing experiment ofindustry.Keyword:coking wax oil;comp