石墨炉原子吸收法测定卷烟主流烟气中的砷、铅、镉、铬、镍.PDFVIP

38 5 () Vol.38 No.5 2012 10 Journal of Hunan Agricultural University (Natural Sciences) Oct 2012 DOI:10.3724/SP.J.1238.2012.00562 石墨炉原子吸收法测定卷烟主流烟气中的 砷、铅、镉、铬、镍 1 2 2 2 2* 1* (1. 266003 2. 250100) 摘 要– 6.298.29 ng/L0.93%4.87%83.44%115.53% 5 关 键 词 + 中图分类号O655.1 1 文献标志码A 文章编号1007–1032(2012)05–0562–05 Determination of arsenic, lead, cadmium, chromium, nickel in mainstream smoke of cigarette by graphite furnace atomic absorption spectrometry 1 2 2 2 2* 1* ZHOU Wen , XU Kai-lin , YUE Yong , XU Hai-tao , ZHOU Shi-lu , WANG Dong-feng (1. College of Food Science and Engineer, Ocean University of China, Qingdao, Shandong 266003, China; 2. Technology Center , China Tobacco Shandong Industrial Co., Ltd. , Jinan 250100, China) Abstract: A method based on graphite furnace atomic absorption spectrometry after microwave digestion for determining arsenic (As), lead (Pb), cadmium (Cd), chromium (Cr) and nickel (Ni) in mainstream smoke of cigarette was developed by optimizing microwave digestion, matrix modifier, ashing temperature and atomic temperature. Under the optimized conditions, the detection limits of the method for As, Pb, Cd, Cr and Ni were 0.008 29, 0.008 12, 0.006 29, 0.006 33 and 0.007 23 µg/L, respectively. The relative standard deviations were 3.14%-4.17% for As, 2.63%-4.12% for Pb, 0.93%-4.45% for Cd, 3.76%-4.29% for Cr and 1.44%-4.87% for Ni. The recoveries of the method for As, Pb, Cd, Cr and Ni were 97.75%-115.40%, 83.44%-118.43%, 83.71%-113.05%, 101.72%-107.03% and