微量元素地球化学课件中国地质大学3碎微量元素在主要地质作用过程中的活动行为.pptVIP

* * * * * * * * * * * * * * * * * Rayleigh: Crystals form and accumulate - isolated from reaction with the remaining liquid * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * D = 1.0 No fractionation so CL/CO = 1 for all values of F * Values of F 0.4 unlikely for batch melting since greater amounts should separate and rise * Highly incompatible elements are greatly concentrated in the initial small fraction of melt that is produced by partial melting, and subsequently get diluted as F increases * All - 1.0 because all of the source is melted * If know (CL) for magma derived by a small degree of batch melting, and we know D, we can estimate the concentration of that element in the source region (CO). This can provide very valuable information in constraining and characterizing the source region. * * * * Suppose that a source rock with a mode of 51% plagioclase, 33% clinopyroxene, and 18% olivine undergoes batch melting * * Rb is incompatible and Sr only slightly so, but near unity * * Results: Incompatible element Rb (no K minerals) strongly concentrated in the early small melt proportions (low F) Thus ? a sensitive measure of the progress of fractional crystallization (at least until rock half melted) As melting proceeds, the incompatible element is gradually diluted by more compatible ones Since D(Sr) is close to 1.0, the ratio Rb/Sr vs. F is nearly the same as Rb alone Any ratio of incompatible to compatible element should then be sensitive to the degree of partial melting (at least in the initial stages). Important for Rb/Sr isotopic systems Note that can create a series of melts from a single source each with diff Rb/Sr * * * * * * * * * * * Incremental batch melting in reverse Equation 9-5 would still apply Batch FX: F = proportion of liquid remaining * 开放体系中微量元素变化的特征 微量元素的地球化学行为取决于矿物相的变化； 矿物相的改变引起元素的重新分配； 温度、压力条件决定元素的分配特征； 流体的加入 流体的释放 元素在流体和矿物相之间的分配 1 10 100 1000 1 10 100 1000 DNb DTa Green and Pearson (1987) Green (200