热解法制备碱式碳酸镁-中南大学学报.PDF

第 39 卷第 5 期 中南大学学报自然科学版( ) Vol.39 No.5 2008 年 10 月 J. Cent. South Univ. (Science and Technology) Oct. 2008 热解法制备碱式碳酸镁 陈白珍，江剑兵，徐 徽，石西昌，吴保安 ( 中南大学 冶金科学与工程学院，湖南 长沙，410083) 摘 要：以盐湖水氯镁石氨法一次沉镁后的母液经碳酸氢铵二次沉镁得到的复盐MgCO ·(NH ) CO ·H O为原料， 3 4 2 3 2 采用热解法制备碱式碳酸镁。研究液固比、Mg2+用量、预氨量、热解温度和热解时间对产品质量的影响。研究结 果表明：在液固比为 6，Mg2+实际用量与理论用量的摩尔比为 1׃1，热解温度为 90~100 ℃，预氨量为 0.2 mL/g复 盐和热解时间为 4.0 h 的工艺条件下得到的碱式碳酸镁质量达到HG/T 2959—2000 标准，该工艺可作为盐湖水氯镁 石制备碱式碳酸镁的有效方法。 关键词：碱式碳酸镁；复盐；热解；水氯镁石；碳酸氢铵；卤水 中图分类号：TF111 文献标识码：A 文章编号：1672−7207(2008)05−0907−06 Preparation of basic magnesium carbonate by pyrogenation CHEN Bai-zhen, JIANG Jian-bing, XU Hui, SHI Xi-chang, WU Bao-an (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: Basic magnesium carbonate was prepared by pyrolyzing MgCO ·(NH ) CO ·H O which was made from the 3 4 2 3 2 mother liquid produced during precipitating Mg2+ from saline bischofite by ammoniation. Ammonium acid carbonate was used as the precipitation agent when MgCO ·(NH ) CO ·H O was prepared. The effects of liquid to solid ratio, ammonia 3 4 2 3 2 amount used for pre-aminating, pyrogenation temperature and time on the product quality were investigated. The results show that under the condition of liquid to solid ratio 6, Mg2+ molar ratio of practical to theoretic usage 1׃1, ammonia amount used for pre-aminating 0.2 mL (correspond