锂离子电池用聚丙烯烃隔膜的表面处理及修饰-物理化学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 ABSTRACTPolyolefin ABSTRACT Polyolefin microporous membrane is commonly used in lithium ion batteries and its advantages with good mechanical properties and chemical stability,and has hi曲performance of autism and to strengthen the safety of battery for daily use．But it also has disadvantages，such觞low wettability,poor electrolyte retention,low ionic conductivity,which limits the further improvement of the performance of the lithium-ion battery．In order to overcome these shortcomings，it is commonly used in the literature to introduce hydrophilic groups the surface of the diaphragm to improve the wettability of the membrane by gra_Ring of plasma treatment,graRing of UV light and other radiation．Howeverthe processing equipment prices ale relatively high,the process is cumbersome and the cost of raw materials is relatively high,thus difficult to scale them up．Therefore，we have explored kind of non-radiation chemical method to preprocess the surface of polypropylene microporous membrane to improve the wettability of polyolefin microporous membrane．Then the method of layer by layer assembly modified with several layers of ionic conducting polymer the surface of the diaphragm and to improve membrane wettability, imbibition rate and fluid retention rate，and improve the conductivity of the batteries．Followed by the membrane surface modifying graphene oxide(GO)and the ion conductive polymer to improve wettability while preventing the negative electrode of lithium dendrite penetration,increasing the metal lithium鹤the anode ofthe battery cycles，which suppressed lithium dendrite growth．Details are嬲follows： (1)LRhium-ion battery separator(polypropylene mieroporous membrane)pre-treatment：In order to make the surface of the polypropylene microporous membrane form polarized chemical group， the infiltration of the electrolyte is improved,and the ion conducting polymer other functional materials ale also easy to be modified at the later stage in the membrane surface．Th