过渡金属离子掺杂改性Cu2ZnSnS4基薄膜太阳 电池的研究进展.pdf

Advances in Condensed Matter Physics 凝聚态物理学进展, 2018, 7(2), 49-57 Published Online May 2018 in Hans. /journal/cmp /10.12677/cmp.2018.72007 Research Progress on Transition Metals Substitution in Cu ZnSnS -Based Thin 2 4 Film Solar Cells Cunpeng Qin, Shuhong Sun, Yongmao Hu, Yan Zhu* Kunming University of Science and Technology, Kunming Yunnan th th th Received: Mar. 20 , 2018; accepted: Apr. 27 , 2018; published: May 4 , 2018 Abstract Cu ZnSnS -based photovoltaic materials have a wide range of application prospects in solar cells 2 4 due to its excellent properties. However, the close size of the cations in the CZTS system and the small chemical mismatch between Cu+ and Zn2+ result in a large number of point defects and defect clusters, leading to a large open-circuit voltage(Voc) deficit in the CZTS that limits its efficiency. The substitution of transition metals Cd, Fe, Mn, Co, Ni and other elements is of great significance for the improvement of the photoelectric properties of Cu ZnSnS -based thin film. Proper cation substitu- 2 4 tion can overcome the large open-circuit voltage (Voc) deficit in CZTS materials, while changing the cation substitution concentration can adjust the bandgap structure. Through the substitution of dif- ferent elements, better photoelectric properties can be achieved. By analyzing the influence of dif- ferent substitution elements and substitution concentration on the photoelectric properties of CZTS-based thin film, the recent research progresses on transition metals (Cd, Fe, Mn, Co, Ni) substi- tution in Cu ZnSnS -based thin film solar cells are review