基于阳极氧化的不锈钢表面多孔层的制备-材料加工工程专业论文.docxVIP

优秀毕业论文 精品参考文献资料 广东工业大学硕士学位论文Abstract 广东工业大学硕士学位论文 Abstract Anodic oxidation can be used to produce porous structure on aluminum and titanium，and the special oxidation porous structure is widely used as template or substrate to assemble all kinds of function materials such as optical material， semiconductor materials，vertical magnetic recording materials by depositing metal， nonmetal，semiconductor materials，magnetic particle，and SO on in its holes．At present， there is no report about the anodizing research of porous structure on the stainless steel surface． This paper researched the anodic oxidation on stainless steel in nitric acid and phosphoric acid electrolyte，studied the process conditions and how the process conditions effect on the microstructure of porous anodic oxidation layer of stainless steel． Formation mechanisms of surface microstructure were analyzed，and the wear resistances of the anodic oxidation layers were studied． Porous structure cannot be formed on stainless steel surface by anodic oxidation in nitric acid electrolyte because the oxide film is very thin．When the current density is small，the oxide film on stainless steel surface cannot be dissolved，while the current density increasing gradually,the oxide film on the surface of stainless steel is partially dissolved and becomes the corrugated morphology．Continue to increase current density, the corrugated morphology was further dissolved and becomes tile structure．When the tile structure oxide film partially dissolved and penetrated，the electrolyte permeate down to the film and corrode the stainless steel and forill circular holes． Porous structure can be formed on stainless steel surface by anodic oxidation in phosphate electrolyte and the structure of porous layer is very similar to that of aluminum and there are 5-7 holes around each hole，but the diameter of the hole on stainless steel is larger than that on aluminum．Pore size decreases with the increase of electrolyte concentration，and anodic