环氧改性丙烯酸树脂乳液的制备和性能研究包装工程.pdf

第36卷 第23期 包装工程 2015年12月 PACKAGINGENGINEERING 1 环保与功能油墨专题 环氧改性丙烯酸树脂乳液的制备和性能研究 辛秀兰，于洋，徐宝财，贺丹，程雪华，吴涛，禹晓燕 （北京工商大学，北京 100048） 摘要：目的目的研究环氧树脂E44改性丙烯酸树脂乳液的添加量和核壳设计温度对乳液性能的影响规 律。方法方法 采用自由基聚合方法合成环氧树脂E44改性丙烯酸酯乳液，并进行乳液红外、吸水率、干燥 性、附着力粒径等方面的性能测试。结果结果 乳液在聚合物薄膜上的附着力随着E44添加量的增加而变 强；吸水率随着E44添加量的增加先变差后变好，在添加量（质量分数）为5%时有最低值7.41%；乳液 的干燥性会随着E44添加量的不同而变化，无明显规律，但是添加量为5%时干燥性最好。结论结论 环氧 树脂E44的添加量为5%。核层设计温度为83℃，壳层设计温度为-11℃时，合成的环氧树脂E44改 性丙烯酸酯乳液的粒径为59nm，吸水率为9.2%，表面张力为35.5mN/m；乳液的干燥性、稳定性和在 聚合物薄膜PVC和PET上的附着力好。 关键词：环氧树脂；丙烯酸酯乳液；包装薄膜；水性连接料 中图分类号：TS802.3 文献标识码：A 文章编号：1001-3563（2015）23-0001-06 Preparation and Properties of Polyacrylate Emulsion Modified by Epoxy Resin XINXiu-lan，YUYang，XUBao-cai，HEDan，CHENGXue-hua，WUTao，YUXiao-yan （Beijing Technology and Business University ，Beijing 100048，China） ABSTRACT ：This paper studied the influence pattern of the adding content of epoxy resin E44 modified polyacrylate emulsion and the core-shell design temperature on the emulsion performance. The epoxy resin E44 modified polyacrylate emulsion was synthesized by radical polymerization. The performance tests of infrared ray, water absorbance, dryness and adhesive particle size were conducted. The adhesion of the emulsion on the poly film was stronger with the increase of the adding amount of epoxy resin E44. The water absorbance firstly got worse then become better along with the adding of epoxy resin E44 and reached to the lowest value of 7.41% at the adding amount (mass fraction) of 5% . The dryness fluctuated with the adding of epoxy resin E44, showing no obvious patterns. The dryness was the best at the adding amount of 5%. In conc