一维纳米tio2的制备及染料废水但脱色分析.docx

一维纳米Ti02的制备及染料废水脱色研究摘 一维纳米Ti02的制备及染料废水脱色研究 摘 要 纳米Ti02因其独特的优势而受到学者们的重视，它不仅能应用于太阳能电池，而 且能应用于环境工程领域，发挥光催化处理废水的重要作用。本文制备了Dy掺杂 Zi02纳米管和以纳米NiFe204为磁性载体的Dy掺杂磁性Ti02纳米管，利用XRD、 TEM、XPS、DSC．TG等表征方法研究了制备条件对纳米管形貌和组成的影响，探讨 了纳米管的组成和结构与光催化性能的关系，并研究了其对染料废水的脱色性能。 以Ti02为原料，采用水热法制备了Dy掺杂Ti02纳米管。XRD、TEM和XPS的 分析结果表明：Dy掺杂Ti02纳米管外径约12nm，壁厚3nm，长300nm，纳米管的主 要组成为Ti02和钛酸盐。Dy掺入了Ti02晶格中，以DyETi05的形式存在。光催化降 解亚甲基蓝的实验结果表明：Dy的摩尔掺杂比为0．8％的前躯体经过360℃煅烧，再水 热反应48h后，制成的Zi02纳米管光催化剂对初始浓度为100mg／L亚甲基蓝的去除量 为1 49．6mg／g。 采用液相沉淀法制备了磁性材料NiFe204，以Ti02／NiFe204为原料，采用水热法 制备了Dy掺杂磁性Ti02纳米管。XRD、TEM和XPS的分析结果表明：该磁性纳米 Ti02具有纳米管形貌，外径约13．5nm，壁厚2．5nm，长350nm：在表面没有检测到 Fe和Ni元素，NiFe204可能进入到纳米管中，纳米管呈弱磁性。磁性离子掺入后Dy 的最佳摩尔掺杂比为O．3％，对亚甲基蓝废水的去除量为88mg／g。NiFe204的复合提高 了催化剂的回收率，可达95．6％。 关键词：Ti02纳米管；磁性；Dy掺杂；亚甲基蓝废水 哈尔滨丁程大学硕十学位论文AB 哈尔滨丁程大学硕十学位论文 AB STRACT Nano Ti02 is highly favored by researchers for its special properties．It has applications in the production of solar batteries and also can be used in the realm of environmental engineering，as a effective catalyst in the photo—catalytical treatment of wastewater．In this paper,Ti02 nanotube doped with Dy and Dy doped magnetic Ti02 nanotube carried by nano NiFe204 magnetic carder were prepared，and effects of preparing conditions on the configurmion and composition of the nanotube were studied嘶tll XRD，TEM，XPS and DSC— TG methods．The relationship between the composition and structure of the nanotube and its photo-catalytical performance Was discussed，and its decolorization capability of dyeing wastewater Was also studied． Zi02 nanotube doped with Dy Was prepared using Ti02 as raw material by Hydrothermal Method．The testing results of XRD，TEM and XPS showed that the external diameter of the nanotube was 12 nm，the wall thickness Was 3 am，the length was 300珈m and the main composition of the nanotube were Ti02 and titanate．Dy Was doped into Ti02 crystal lattice and existed in the form of Dy2TiOs．The experimental results of photo—catalytical degradation of Methylene Blue wastewater showed that：for the prec